Electrical and optical properties of poly(acrylamide-co-acrylic acid) based polymer electrolytes containing water-soluble potassium iodide salt

被引：2

作者：

Lee, Y. C. ^{[1
]}

Buraidah, M. H. ^{[1
,3
]}

Woo, H. J. ^{[1
]}

Teo, L. P. ^{[2
]}

机构：

[1] Univ Malaya, Ctr Ion Univ Malaya, Fac Sci, Dept Phys, Kuala Lumpur, Malaysia

[2] Tunku Abdul Rahman Univ Management & Technol, Fac Appl Sci, Dept Phys Sci, Jalan Genting Kelang, Kuala Lumpur, Malaysia

[3] Univ Malaya, Ctr Ion Univ Malaya, Fac Sci, Dept Phys, Kuala Lumpur 50603, Malaysia

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2023年 / 760卷 / 01期

关键词：

Fourier transform infrared (FTIR) spectroscopy; ionic conductivity; Poly(acrylamide-co-acrylic acid; potassium iodide; solid polymer electrolyte; SENSITIZED SOLAR-CELLS; ION-TRANSPORT; POLYACRYLAMIDE; KI;

D O I：

10.1080/15421406.2023.2166135

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly(acrylamide-co-acrylic acid) (PAAm-PAA) based solid polymer electrolytes (SPEs) containing potassium iodide (KI) have been prepared. The complexation between PAAm-PAA and KI has been identified through the position changes at the asymmetric NH2 stretching and CH2 stretching; and the intensities changes at the amide (C = O, C-N) and carboxylate (COO-) bands using Fourier transform infrared (FTIR) spectroscopy. PAAm-PAA film exhibits a room temperature (RT) ionic conductivity of (8.8 +/- 0.8) x 10(-11) S center dot cm(-1) which increases to maximum at (4.0 +/- 0.5) x 10(-7) S center dot cm(-1) with 45 wt.% KI addition. The conductivity-temperature dependence studies of all samples followed the Arrhenius rule.

引用

页码：51 / 59

页数：9

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