Efficient adsorption of Ce (III) using cellulose graft poly (2-acrylamido-2-methyl-1-propanesulfonic acid)/graphene oxide composite

被引:3
|
作者
Huang, Tianwen [1 ]
Qu, Jing [1 ]
Tan, Lei [1 ]
Yao, Rui [1 ]
Jiao, Wenyue [1 ]
Wang, Yicheng [2 ]
Lin, Tingrui [2 ,3 ]
Hao, Yan [1 ]
Yang, Hui [1 ]
Yang, Huimin [1 ]
Sai, Huazheng [1 ]
机构
[1] Inner Mongolia Univ Sci & Technol, Inst Appl Chem Sch Chem & Chem Engn, Sch Chem & Chem Engn, Baotou 014010, Peoples R China
[2] Peking Univ, Coll Chem & Mol Engn, Radiochem & Radiat Chem Key Lab Fundamental Sci, Beijing Natl Lab Mol Sci,Minist Educ,Key Lab Polym, Beijing 100871, Peoples R China
[3] Skshu Paint Co Ltd, Fujian Key Lab Architectural Coating, Putian 351100, Fujian, Peoples R China
基金
中国国家自然科学基金;
关键词
Composite; Cellulose; Poly (2-acrylamido-2-methyl-1-propanesulfonic acid); Graphene oxide; Adsorption; Ce (III) removal; RARE-EARTH-ELEMENTS; GRAPHENE OXIDE; AQUEOUS-SOLUTIONS; CRYSTAL VIOLET; ADSORBENT; CERIUM; CE(III); RESIN; EQUILIBRIUM; PERFORMANCE;
D O I
10.1016/j.colsurfa.2023.132981
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel cellulose grafted poly (2-acrylamido-2-methyl-1-propanesulfonic acid) /graphene oxide composite adsorbent (CPAG) was synthesized and applied for the removal of Ce (III) from aqueous solution. The resultant CPAG was characterized by FTIR, XRD, Raman spectroscopy, TGA, SEM and XPS. Adsorption studies demonstrated the adsorption equilibrium could be achieved within 25 min. The optimum adsorption capacity of CPAG for Ce (III) reached 271.8 mg & sdot;g-1, which displayed enhanced adsorption performance and relatively faster adsorption rate. The adsorption process could be described well by the pseudo-second-order kinetic model and Langmuir isotherm model. The adsorption mechanism was found to depend on ion exchange. In addition, CPAG maintained the comparative adsorption capacity and good reusability after four consecutive adsorptiondesorption cycles. The research results suggested that CPAG was efficient in the adsorption of Ce (III), which
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页数:10
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