Template Synthesis of Polyaniline in the Presence of Poly-(2-acrylamido-2-methyl-1-propanesulfonic Acid)

A template oxidative polymerization of aniline in aqueous solutions containing poly-(2-acrylamido-2-methyl-1-propanesulfonic acid) and ammonium persulfate yields a polyaniline complex with the polyacid soluble in water. According to the data of spectral measurements, the process of polymerization is of a pronounced autocatalytic nature. The consequences of this are both the formation of a nonuniform distribution of oxidized and nonoxidized fragments of the polymer chain and the formation of a macroscopic scale of redox nonuniformities in the reaction volume during the process of polymerization. The spectra of absorption of the polyaniline/polyacid films on transparent glass electrodes with a conductive layer of SnO2 and the data of potentiodynamic measurements in the potential region 0–1.0 V (Ag/AgCl) are typical for polyaniline with moderate electroconduction.