The CdS/CaTiO3 cubic core-shell composite towards enhanced photocatalytic hydrogen evolution and photodegradation

被引：15
|
作者：
Yang, Hu [1 ]
Li, Xinyan [2 ]
Zhao, Tianli [1 ]
Peng, Qiying [1 ]
Yang, Wenhui [1 ]
Cao, Jun [1 ]
Zheng, Yingying [1 ]
Li, Chaorong [1 ]
Pan, Jiaqi [1 ]
机构：
[1] Zhejiang Sci Tech Univ, Dept Phys, Key Lab Opt Field Manipulat Zhejiang Prov, Hangzhou 310018, Peoples R China
[2] Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Peoples R China
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2023年 / 48卷 / 57期
基金：
中国国家自然科学基金;
关键词：
Core-shell composite; HER; Photodegradation; Stability; SURFACE MODIFICATION; NANOWIRES; G-C3N4;
D O I：
10.1016/j.ijhydene.2023.03.076
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The CdS/CaTiO3 cubic core-shell composite is synthesized via a hydrothermal-chemical method. The CdS/CaTiO3 cubic core-shell composite (CdS/CTO-2) exhibits remarkable photocatalytic HER activity (-1025.27 mmol$g �1 h-1) and photodegradation enhancement than that of single CaTiO3 (-21 folds of HER,-19 folds of photodegradation) and single CdS (-15 folds of HER,-15 folds of photodegradation), and a decent stability. There, CdS/CaTiO3 composite with appropriate potential gradient and CdS with better visible light response can improve carrier efficiency, including increasing carrier transportation, prolonging lifetime and decreasing recombination. Additionally, cubic core-shell microstructure can increase active sites, while maintaining photocatalytic stability.& COPY; 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：21788 / 21798
页数：11
相关论文
共 50 条
  • [31] Construction of CdS/CoOx core-shell nanorods for efficient photocatalytic H2 evolution
    Liu, Ye
    Ding, Shuoping
    Shi, Yiqiu
    Liu, Xiufan
    Wu, Zuozuo
    Jiang, Qingqing
    Zhou, Tengfei
    Liu, Nikang
    Hu, Juncheng
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 234 : 109 - 116
  • [32] Ternary Co3O4/CdS/SrTiO3 core-shell pn junctions toward enhanced photocatalytic hydrogen production activity
    Chen, Zhanfen
    Pan, Jiaqi
    Mei, Jie
    Yu, Qi
    Wang, Panhong
    Wang, Peipei
    Wang, Jingjing
    Song, Changsheng
    Zheng, Yingying
    Li, Chaorong
    JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2021, 9 (01):
  • [33] Ascorbic acid functionalized CdS-ZnO core-shell nanorods with hydrogen spillover for greatly enhanced photocatalytic H2 evolution and outstanding photostability
    Sun, Guotai
    Xiao, Bing
    Zheng, Hong
    Shi, Jian-Wen
    Mao, Siman
    He, Chi
    Li, Zhihui
    Cheng, Yonghong
    JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (15) : 9735 - 9744
  • [34] Noble-metal-free amorphous CoMoSx modified CdS core-shell nanowires for dramatically enhanced photocatalytic hydrogen evolution under visible light irradiation
    Li, Qiuhao
    Qiao, Xiu-Qing
    Jia, Yanlin
    Hou, Dongfang
    Li, Dong-Sheng
    APPLIED SURFACE SCIENCE, 2019, 498
  • [35] Understanding oxygen vacancies in disorder-engineered surface and subsurface of CaTiO3 nanosheets on photocatalytic hydrogen evolution
    Cai, Jinmeng
    Cao, Ang
    Huang, Jingjing
    Jin, Wenfeng
    Zhang, Jing
    Jiang, Zheng
    Li, Xingang
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 267
  • [36] Hydrothermal synthesis of core-shell TiO2 to enhance the photocatalytic hydrogen evolution
    Jiang, Jinghui
    Zhou, Han
    Zhang, Fan
    Fan, Tongxiang
    Zhang, Di
    APPLIED SURFACE SCIENCE, 2016, 368 : 309 - 315
  • [37] Effective shuttling of photoexcitons on CdS/NiO core/shell photocatalysts for enhanced photocatalytic hydrogen production
    Reddy, N. Lakshmana
    Rao, V. Navakoteswara
    Kumari, M. Mamatha
    Ravi, P.
    Sathish, M.
    Shankar, M. V.
    MATERIALS RESEARCH BULLETIN, 2018, 101 : 223 - 231
  • [38] Core-shell Cu1.94S-MnS nanoheterostructures synthesized by cation exchange for enhanced photocatalytic hydrogen evolution
    Li, Chongyao
    Wang, Weijia
    Yang, Ying
    Liu, Sheng
    Zhu, Congtan
    Tian, Qinghua
    CRYSTENGCOMM, 2021, 23 (36) : 6291 - 6299
  • [39] A new strategy for constructing covalently connected MOF@COF core-shell heterostructures for enhanced photocatalytic hydrogen evolution
    Zhang, Hong-Yu
    Yang, Yan
    Li, Chang-Cheng
    Tang, Hong-Liang
    Zhang, Feng-Ming
    Zhang, Gui-Ling
    Yan, Hong
    JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (31) : 16743 - 16750
  • [40] Durian-Shaped CdS@ZnSe Core@Mesoporous-Shell Nanoparticles for Enhanced and Sustainable Photocatalytic Hydrogen Evolution
    Lian, Zichao
    Sakamoto, Masanori
    Kobayashi, Yoichi
    Tamai, Naoto
    Ma, Jun
    Sakurai, Tsuneaki
    Seki, Shu
    Nakagawa, Tatsuo
    Lai, Mingwei
    Haruta, Mitsutaka
    Kurata, Hiroki
    Teranishi, Toshiharu
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2018, 9 (09): : 2212 - +
12345