共 50 条
The CdS/CaTiO3 cubic core-shell composite towards enhanced photocatalytic hydrogen evolution and photodegradation
被引:15
|作者:
Yang, Hu
[1
]
Li, Xinyan
[2
]
Zhao, Tianli
[1
]
Peng, Qiying
[1
]
Yang, Wenhui
[1
]
Cao, Jun
[1
]
Zheng, Yingying
[1
]
Li, Chaorong
[1
]
Pan, Jiaqi
[1
]
机构:
[1] Zhejiang Sci Tech Univ, Dept Phys, Key Lab Opt Field Manipulat Zhejiang Prov, Hangzhou 310018, Peoples R China
[2] Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Peoples R China
基金:
中国国家自然科学基金;
关键词:
Core-shell composite;
HER;
Photodegradation;
Stability;
SURFACE MODIFICATION;
NANOWIRES;
G-C3N4;
D O I:
10.1016/j.ijhydene.2023.03.076
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The CdS/CaTiO3 cubic core-shell composite is synthesized via a hydrothermal-chemical method. The CdS/CaTiO3 cubic core-shell composite (CdS/CTO-2) exhibits remarkable photocatalytic HER activity (-1025.27 mmol$g �1 h-1) and photodegradation enhancement than that of single CaTiO3 (-21 folds of HER,-19 folds of photodegradation) and single CdS (-15 folds of HER,-15 folds of photodegradation), and a decent stability. There, CdS/CaTiO3 composite with appropriate potential gradient and CdS with better visible light response can improve carrier efficiency, including increasing carrier transportation, prolonging lifetime and decreasing recombination. Additionally, cubic core-shell microstructure can increase active sites, while maintaining photocatalytic stability.& COPY; 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:21788 / 21798
页数:11
相关论文