Gibbs equilibrium conditions and the thermodynamic limit

被引:0
|
作者
Zabashta, Yuri F. [1 ]
Lazarenko, Maxim M. [1 ]
Alekseev, Alexander N. [1 ]
Yablochkova, Kateryna S. [1 ]
Shevchenko, Victoria B. [1 ]
Bulavin, Leonid A. [1 ]
Shevchenko, Taras [1 ]
机构
[1] Natl Univ Kyiv, 64,Volodymyrska St, UA-01601 Kiev, Ukraine
关键词
Gibbs equilibrium conditions; Thermodynamic limit; Heterophase body; Homophase system; Phase transition temperature;
D O I
10.1016/j.chemphys.2024.112193
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present work we critically examine a structural model of a heterophase body, whose equilibrium is described by the equations of Gibbs equilibrium conditions. We demonstrate that these equilibrium conditions describe the behaviour of the heterophase body in a thermodynamic limit. Additionally, these equations can be viewed as the phase transition conditions from any homophase system that make up the heterophase body. In light of the proposed interpretation of Gibbs equilibrium conditions, we offer a new way to define phase transition temperature.
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页数:4
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