Co(III) Intermediates in Cobalt-Catalyzed, Bidentate Chelation Assisted C(sp2)-H Functionalizations

被引:8
|
作者
Cizikovs, Aleksandrs [1 ]
Grigorjeva, Liene [1 ]
机构
[1] Latvian Inst Organ Synth, Aizkraukles 21, LV-1006 Riga, Latvia
关键词
cobalt; C-H bond functionalization; Co(III) intermediate; C-H FUNCTIONALIZATION; GROUP MIGRATION; ANNULATION; CARBONYLATION; ACCESS;
D O I
10.3390/inorganics11050194
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The C-H bond activation and functionalization is a powerful tool that provides efficient access to various organic molecules. The cobalt-catalyzed oxidative C-H bond activation and functionalization has earned enormous interest over the past two decades. Since then, a wide diversity of synthetic protocols have been published for C-C, C-Het, and C-Hal bond formation reactions. To gain some insights into the reaction mechanism, the authors performed a series of experiments and collected evidence. Several groups have successfully isolated reactive Co(III) intermediates to elucidate the reaction mechanism. In this review, we will summarize information concerning the isolated and synthesized Co(III) intermediates in cobalt-catalyzed, bidentate chelation assisted C-H bond functionalization and their reactivity based on the current knowledge about the general reaction mechanism.
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页数:23
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