4-ATP-modified CNTs@NiO-Fe2O3-Ag SERS filter membrane for rapid in-situ detection of furfural in mineral oil

Evaluating the transformer aging state and detecting multi-aging characteristics in transformer oil with high sensitivity and fast speed has become a key challenge. This study introduces a P-N heterojunction (CNTs@NiO-& alpha;-Fe2O3) fabricated through electroless nickel plating and a one-step hydrothermal method. Additionally, silver nanoparticles (AgNPs) with adjustable particle sizes are grown on the surface using a chemical reduction method. To obtain high sensitivity and rapid SERS signal, CNTs@NiO-& alpha;-Fe2O3-Ag gel is adsorbed on a disposable needle filter (220 nm) surface, and 4-aminothiophene (4-ATP) is grafted onto the surface of SERS substrate. The minimum detection limit was 0.025 mg/L (EF = 5.22 x 104), and the response time of SERS best signal could be shortened to 3 min. Density functional theory (DFT) calculations reveal that by constructing a P-N hetero-structure of NiO-Fe2O3 and assessing the adsorption energies of furfural, acetone, and methanol on the surface of the P-N heterojunction. This SERS strategy has a huge application prospect in the aging diagnosis of oil-paper insulation systems in a transformer.