Two-dimensional ZnII coordination polymer based on 5-iodoisophthalate: synthesis, crystal and electronic structure

被引：2

作者：

Zaguzin, A. S. ^{[1
,2
]}

Spiridonova, D. V. ^{[3
]}

Novikov, A. S. ^{[4
]}

Rakhmanova, M. I. ^{[1
]}

Zherebtsov, D. A. ^{[2
]}

Fedin, V. P. ^{[1
]}

Adonin, S. A. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, 3 Prosp Akad Lavrentieva, Novosibirsk 630090, Russia

[2] South Ural State Univ, 76 prosp Lenina, Chelyabinsk 454080, Russia

[3] St Petersburg State Univ, Res Pk,7-9 Universitetskaya nab, St Petersburg 199034, Russia

[4] St Petersburg State Univ, Inst Chem, 7-9 Universitetskaya nab, St Petersburg 199034, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2023年 / 72卷 / 01期

基金：

俄罗斯科学基金会;

关键词：

zinc; carboxylates; complexes; halogen bond; METAL-ORGANIC FRAMEWORKS; SIGMA-HOLE DONOR; ZN(II)-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; LIGAND SYNTHESIS; DIARYLIODONIUM; COMPLEXES; TEMPERATURE; NICKEL(II); FRAGMENTS;

D O I：

10.1007/s11172-023-3722-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of zinc(II) nitrate with 5-iodoisophthalic acid (5-I-IPAH) in N,N-dimethylformamide afforded the layered coordination polymer {Zn(5-I-IPA)}(n)(1). The structure of 1 was determined by single-crystal X-ray diffraction. The phase purity of 1 was confirmed by powder X-ray diffraction. The molecular electrostatic potentials of iodine atoms, which characterize their ability to form a halogen bond, were determined by quantum chemical calculations.

引用

页码：177 / 183

页数：7

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