Transition-Metal-Free Upscaling of 2,5-Furandicarboxylic Acid Synthesis and Investigation of the Reaction Mechanism

被引：0

作者：

Lee, Tae Woo ^{[1
]}

Lee, Won Jung ^{[2
,3
]}

Kim, Young Sug ^{[1
]}

Do, Taeyang ^{[1
]}

Choi, Ji-Eun ^{[2
]}

Han, Young Kwang ^{[1
]}

Oh, Chunrim ^{[2
]}

Lee, Chi-Wan ^{[2
]}

Yum, Eul Kgun ^{[3
]}

Yang, Jung Woon ^{[1
]}

机构：

[1] Sungkyunkwan Univ, Dept Energy Sci, Suwon 16419, South Korea

[2] Samyang Corp, Chem Res Ctr, Daejeon 34055, South Korea

[3] Chungnam Natl Univ, Dept Chem, Daejeon 34134, South Korea

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2023年 / 29卷 / 36期

基金：

新加坡国家研究基金会;

关键词：

biomass; FDCA; sustainability; transition-metal-free; upgrading process; SELECTIVE AEROBIC OXIDATION; SUSTAINABLE MANUFACTURE; HIGHLY EFFICIENT; VALUE CHEMICALS; AQUEOUS-PHASE; AIR-OXIDATION; SUPPORTED AU; BIOMASS; CATALYST; CONVERSION;

D O I：

10.1002/chem.202300903

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An environmentally friendly oxidation system has proposed for the practical and scalable production of value-added 2,5-furandicarboxylic acid from 1 kg of 5-hydroxymethylfurfural. The system is composed of a simple base, oxygen, and a green solvent, thereby providing a sustainable and economical approach to organic synthesis. To gain insight into the mechanism of this oxidation process, NMR spectroscopic analysis and kinetic study are used for the mechanistic investigation of this environmentally friendly oxidation process.

引用

页数：6

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