2,5-Furandicarboxylic Acid: An Intriguing Precursor for Monomer and Polymer Synthesis

被引：27
|
作者：
Marshall, Adam [1 ]
Jiang, Bo [1 ]
Gauvin, Regis M. [1 ]
Thomas, Christophe M. [1 ]
机构：
[1] PSL Univ, Chim ParisTech, CNRS, Inst Rech Chim Paris, F-75005 Paris, France
来源：
MOLECULES | 2022年 / 27卷 / 13期
关键词：
biobased monomers; sustainable polymers; furan-based materials; DECOMPOSITION MECHANISM; BIOMASS; POLYESTERS; CONVERSION; HUMINS; ETHERIFICATION; CARBOXYLATION; VALORIZATION; DEGRADATION; COMPONENTS;
D O I：
10.3390/molecules27134071
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The most versatile furanic building block for chemical and polymer applications is 2,5-furandicarboxylic acid. However, the classical 2,5-furandicarboxylic acid production methodology has been found to have significant drawbacks that hinder industrial-scale production. This review highlights new alternative methods to synthesize 2,5-furandicarboxylic acid that are both more advantageous and attractive than conventional oxidation of 5-hydroxymethylfurfural. This review also focuses on the use of 2,5-furandicarboxylic acid as a polymer precursor and the various potential applications that arise from these furan-based materials.
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页数：24
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