Porous activated carbon derived from petroleum coke as a high-performance anodic electrode material for supercapacitors

被引:4
|
作者
Pati, Subir K. [1 ]
Hwang, Yejin [1 ]
Lee, Hye-Min [2 ]
Kim, Byung-Joo [3 ]
Park, Sungjune [1 ]
机构
[1] Jeonbuk Natl Univ, Dept Nano Convergence Engn, Dept Polymer Nano Sci & Technol, Jeonju 54896, South Korea
[2] Korea Carbon Ind Promot Agcy, R&BD Grp 1, Industrializat Div, Jeonju 54853, South Korea
[3] Jeonju Univ, Dept Adv Mat & Chem Engn, Jeonju 55069, South Korea
关键词
Pitch carbon; Coke carbon; Porous activated carbon; Electric double-layer capacitor; Supercapacitor; CHEMICAL ACTIVATION; PORE DEVELOPMENT; PALM-SHELL; ENERGY;
D O I
10.1007/s42823-023-00628-7
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In recent times, there has been a significant demand for supercapacitors in energy storage applications due to their rapid charging-discharging capabilities, high power density, and excellent stability. Nevertheless, the synthesis of electrode materials with a substantial surface area, exceptionally high porosity, and superior electrochemical performance is still challenging. Activated carbons with a distinctive porous structure and exceptional electrochemical properties emerged as promising electrode materials for supercapacitors. In this study, we used a porous activated carbon (PAC) derived from petroleum coke followed by KOH activation as an efficient anodic electrode material. The ultra-high Brunauer-Emmett-Teller surface area of 2105.6 m(2) g(-1) with stacked layers of carbon atoms arranged in a two-dimensional hexagonal structure makes the PAC an efficient candidate for a supercapacitor electrode. The PAC delivers a specific capacitance of 470 F g(-1) at a current density of 0.5 A g(-1) over a potential window of 0 to -1 V. The excellent cycling stability in a three-electrode setup with a capacitance retention of similar to 98% even at a high current density of 10 A g(-1) makes the PAC a potential anodic electrode material for high-performance supercapacitor applications. [GRAPHICS] .
引用
收藏
页码:153 / 162
页数:10
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