Synthesis of Carbamoyl Azides from Redox-Active Esters and TMSN 3

被引：1

作者：

Yuan, Xiaobin ^{[1
,2
]}

Qu, Yanjie ^{[1
,2
]}

Li, Yajun ^{[2
]}

Bao, Hongli ^{[2
]}

机构：

[1] Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350117, Peoples R China

[2] Chinese Acad Sci, Ctr Excellence Mol Synth, Key Lab Coal Ethylene Glycol & Its Related Technol, State Key Lab Struct Chem, 155 Yangqiao Rd West, Fuzhou 350002, Fujian, Peoples R China

来源：

SYNLETT | 2024年 / 35卷 / 04期

基金：

中国国家自然科学基金;

关键词：

redox-active esters; iron catalysis; NHP esters; azidation; carbamoyl azides; DECARBOXYLATIVE COUPLING REACTIONS; ONE-POT SYNTHESIS; C-C; SECONDARY ALCOHOLS; KETONES; ACIDS; COMBINATION; CONVERSION; OXIDATION; CURTIUS;

D O I：

10.1055/a-2106-5108

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient method for construction of C-N bonds is reported here. The iron-catalyzed azidation of N-hydroxy phthalimide (NHP) esters provides a convenient approach for the synthesis of carbamoyl azides with good substrate scope and functional group tolerance. Both aryl carbon C(sp(2)) and alkyl carbon C(sp(3)) sources can be used deliver the carbamoyl azides. Mechanistic studies were conducted and a two-stage process was identified.

引用

页码：464 / 468

页数：5

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