Synthesis of new complex [Bi6O6(OH)2](ClC6H4SO3)4 and investigation of its thermal decomposition

被引：0
|
作者：
Kaloyanov, Nikolay [1 ]
Zahariev, Alexander [2 ]
Parvanova, Veneta [3 ]
Avdeev, Georgi [4 ]
Girginov, Christian [5 ]
机构：
[1] Univ Chem Technol & Met, Dept Organ Chem, 8 St Kliment Ohridski blvd, Sofia 1756, Bulgaria
[2] Tech Univ, Dept Chem, 8 St Kliment Ohridski blvd, Sofia 1000, Bulgaria
[3] Univ Chem Technol & Met, Dept Gen & Inorgan Chem, 8 St Kliment Ohridski Blvd, Sofia 1756, Bulgaria
[4] Bulgarian Acad Sci, Inst Phys Chem Acad Rostislaw Kaischew, ?cad G Bonchev Str,Bldg 11, Sofia 1113, Bulgaria
[5] Univ Chem Technol & Met, Dept Phys Chem, 8 St Kliment Ohridski Blvd, Sofia 1756, Bulgaria
来源：
INDIAN JOURNAL OF CHEMISTRY | 2023年 / 62卷 / 05期
关键词：
Bi(III) complexes; Thermal decomposition; TG-DTA; XRD; FTIR; BISMUTH; CHEMISTRY;
D O I：
10.56042/ijc.v62i5.1434
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new [Bi6O6(OH)2](ClC6H4SO3)4 complex is synthesized through a reaction of Bi2O3 with aqueous 4-chlorobenzenesulfonic acid at elevated temperature. The product composition is elucidated by elemental analysis, ICP-OES and FTIR techniques. By means of XRD analysis, the compound's indexation, monoclinic P2(3) space group and unit cell parameters: a=31.25(3) a, b=19.78(1) angstrom, c=8.795(8) a, y = 94.33(4)o as well as a cell volume = 5424.21 a3 are determined. Based on DTA-TG technique, three specific temperatures aimed at studying product's thermal decomposition are determined. The compositions of solid residues after isothermal heating are proved following the XRD and FTIR data.
引用
收藏
页码：431 / 436
页数：6
相关论文
共 50 条
  • [41] Synthesis of Mo–doped symbiotic mixture of Bi2WO6 and Bi6O6(OH)3(NO3)3·1.5H2O nanosheets with enhanced photocatalytic degradation for mustard gas simulator 2-CEES
    Haoguo Yang
    Yijun Guo
    Shitong Han
    Hailing Xi
    Huaxiang Lin
    Rusheng Yuan
    Zhengxin Ding
    Jinlin Long
    Qun Lin
    Research on Chemical Intermediates, 2023, 49 : 3381 - 3393
  • [42] STUDY OF THERMAL-DECOMPOSITION OF COMPLEX FERRIC FORMATE, -FE-3(HCOO)6(OH)2-HCOO.4H2O
    PESHEV, P
    PECHEVA, M
    MATERIALS RESEARCH BULLETIN, 1978, 13 (05) : 419 - 426
  • [43] Crystal structure of a new mineral lahnsteinite Zn4(SO4)(OH)6 • 3H2O
    Rastsvetaeva, R. K.
    Aksenov, S. M.
    Chukanov, N. V.
    Verin, I. A.
    CRYSTALLOGRAPHY REPORTS, 2012, 57 (05) : 737 - 741
  • [44] Structural and Physicochemical Studies of [4-ClC6H4CH2NH3]4Li2P6O184H2O
    Amri, O.
    Abid, S.
    Rzaigui, M.
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2009, 184 (03) : 766 - 777
  • [45] Crystal structure of a new mineral lahnsteinite Zn4(SO4)(OH)6 · 3H2O
    R. K. Rastsvetaeva
    S. M. Aksenov
    N. V. Chukanov
    I. A. Verin
    Crystallography Reports, 2012, 57 : 737 - 741
  • [46] Synthesis and structural characterisation of new ettringite and thaumasite type phases: Ca6[Ga(OH)6•12H2O]2(SO4)3•2H2O and Ca6[M(OH)6•12H2O]2(SO4)2(CO3)2, M = Mn, Sn
    Norman, Rachel L.
    Dann, Sandra E.
    Hogg, Simon C.
    Kirk, Caroline A.
    SOLID STATE SCIENCES, 2013, 25 : 110 - 117
  • [47] Reactions of nitrosoarenes containing electron-withdrawing substituents with coordinated CO. Synthesis and structure of complexes Pd2(OAc)2(p-ClC6H4N[p-ClC6H3NO])2 and Pd2(OAc)2(o-ClC6H4N[o-ClC6H3NO])2
    S. T. Orlova
    T. A. Stromnova
    D. N. Kazyul"kin
    L. I. Boganova
    D. I. Kochubey
    B. N. Novgorodov
    Russian Chemical Bulletin, 2004, 53 : 819 - 824
  • [48] Tetranuclear bismuth complexes Bi4(O)2(O2CC6H2F3-3,4,5)8 · 2C6H6 and Bi4(O)2(O2CC6H2F3-3,4,5)8 · 2C6H4Me2-1,4: Synthesis and structures
    V. V. Sharutin
    I. V. Egorova
    O. K. Sharutina
    T. K. Ivanenko
    N. Yu. Adonin
    V. F. Starichenko
    M. A. Pushilin
    A. V. Gerasimenko
    Russian Journal of Coordination Chemistry, 2005, 31 : 2 - 8
  • [49] Tetranuclear bismuth complexes Bi4(O)2(O2CC6H2F3-3,4,5)8•2C6H6 and Bi4(O)2(O2CC6H2F3-3,,4,5)8•2C6H4Me2-1,4:: Synthesis and structures
    Sharutin, VV
    Egorova, IV
    Sharutina, OK
    Ivanenko, TK
    Adonin, NY
    Starichenko, VF
    Pushilin, MA
    Gerasimenko, AV
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2005, 31 (01) : 2 - 8
  • [50] Tetranuclear bismuth complexes Bi4(O)2(O2CC6H2F3-3,4,5)8 · 2C6H6 and Bi4(O)2(O2CC6H2F3-3,4,5)8 · 2C6H4Me2-1,4: Synthesis and structures
    V. V. Sharutin
    I. V. Egorova
    O. K. Sharutina
    T. K. Ivanenko
    N. Yu. Adonin
    V. F. Starichenko
    M. A. Pushilin
    A. V. Gerasimenko
    Russian Journal of Coordination Chemistry, 2005, 31 (1) : 2 - 8
12345