Microstructural evolution and tribological behavior of suspension plasma sprayed CuO as high-temperature lubricious coatings

Suspension plasma spraying (SPS) was used to produce three different CuO coatings by varying spray distance and solid loading within the suspension. The low spray distance (30 mm) and high solid loading (20 wt%) in the suspension resulted in the deposition of dense coatings as compared to other spray conditions (i.e., a distance of 40 mm and solid loading of 10 wt%). The tribological performance of the dense coating was investigated at 25 degrees C and 300 degrees C under dry sliding conditions. Scanning electron microscopy (SEM), X-ray diffraction (XRD), and Raman analysis were used to characterize the coating, and corresponding wear tracks to determine the wear mechanisms. The results showed that the friction coefficient of the CuO coating decreased from 0.7 at 25 degrees C to 0.46 at 300 degrees C. Similarly, the wear rate at 300 degrees C decreased by 50% compared to the wear rate at 25 degrees C. Ex-situ analysis showed an increased oxygen content on the worn surfaces at 300 degrees C and the formation of a smooth uniform tribofilm. At 25 degrees C, a thicker transfer film was observed on the counterface, which leads to a different velocity accommodation mode and, thus, relatively high friction.