Synthesis of new ferrocenyl-containing tertiary alcohols, analogs of l-prolinol-based organocatalysts

被引：1

作者：

Burlutsky, Roman O. ^{[1
]}

Yudina, Ella S. ^{[1
]}

Churakov, Andrei, V ^{[2
]}

Lemenovskiy, Dmitriy A. ^{[1
]}

Dyadchenko, Victor P. ^{[1
]}

机构：

[1] M V Lomonosov Moscow State Univ, Dept Chem, Moscow 119991, Russia

[2] Russian Acad Sci, N S Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2024年 / 34卷 / 01期

关键词：

asymmetric organocatalysis; ferrocene; proline; tert-butoxycarbonyl protective group; ferrocenylmagnesium bromide; chiral tertiary alcohols; X-ray molecular structure; ENANTIOSELECTIVE SYNTHESIS; DERIVATIVES; CATALYSTS;

D O I：

10.1016/j.mencom.2024.01.019

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Syntheses of new ferrocenyl-containing tertiary alcohols derived from l-proline were developed. In these alcohols, two ferrocenyl groups are bonded at prolinol moiety directly or through p-phenylene spacer. Specific features for the ferrocene Grignard reagents were discovered.

引用

页码：64 / 66

页数：3

共 9 条

[1] Synthesis, structure and catalytic activity of new ferrocenyl-containing secondary alcohols derived from l-proline
Burlutsky, Roman O.
Yudina, Ella S.
Churakov, Andrei, V
Lemenovskiy, Dmitriy A.
Dyadchenko, Victor P.
MENDELEEV COMMUNICATIONS, 2024, 34 (02) : 201 - 203
[2] The synthesis and structure of new tin(II) complexes based on ferrocenyl-containing o-iminophenols
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Bellan, E. V.
Poddel'sky, A. I.
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[3] The synthesis, structure and electrochemical properties of new cobalt and nickel complexes based on ferrocenyl-containing o-iminophenols
Baryshnikova, S. V.
Poddel'sky, A. I.
Cherkasov, A. V.
Smolyaninov, I. V.
INORGANICA CHIMICA ACTA, 2019, 495
[4] The synthesis and structure of new ferrocenyl-containing o- iminophenol schiff bases and nickel(II), copper(II) bis-o- iminophenolato complexes
Baryshnikova, Svetlana, V
Fukin, Georgy K.
Poddel'sky, Andrey, I
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2020, 923
[5] LIGHT-INDUCED REACTION OF THEXYLDIALKYLBORANES WITH BROMINE IN PRESENCE OF WATER - NEW AND CONVENIENT SYNTHESIS OF TERTIARY ALCOHOLS INCLUDING THOSE CONTAINING FUNCTIONAL SUBSTITUENTS
BROWN, HC
LANE, CF
YAMAMOTO, Y
SYNTHESIS-INTERNATIONAL JOURNAL OF METHODS IN SYNTHETIC ORGANIC CHEMISTRY, 1972, (06): : 304 - &
[6] Developments in organic synthesis based on the reduction intermediates generated from fluorinated esters and DIBAL - New approach to the synthesis of fluorine-containing alcohols
Ishihara, T
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1999, 57 (04) : 313 - 322
[7] Synthesis and characterization of ferrocenylchalcogenopropargyl complexes [Fe(η5-C5H4EICH2CCH)2] (EI = Se, S) and their reactions to form unusual ferrocenyl-containing metal clusters with eclipsed Cp rings and new five-membered FeEICH=CCH2 ring ligand system
Mathur, P
Singh, VK
Mobin, SM
Srinivasu, C
Trivedi, R
Bhunia, AK
Puraniki, VG
ORGANOMETALLICS, 2005, 24 (03) : 367 - 372
[8] The synthesis of new 1,3-oxazolidines and 1,3-oxazinanes containing (η6-arene)tricarbonylchromium group based on condensation between aldehydes and amino alcohols
A. N. Artemov
E. V. Sazonova
N. A. Krylova
E. A. Zvereva
N. A. Pechen
G. K. Fukin
A. V. Cherkasov
V. I. Faerman
N. Yu. Grishina
Russian Chemical Bulletin, 2018, 67 : 884 - 892
[9] The synthesis of new 1,3-oxazolidines and 1,3-oxazinanes containing (η6-arene)tricarbonylchromium group based on condensation between aldehydes and amino alcohols
Artemov, A. N.
Sazonova, E. V.
Krylova, N. A.
Zvereva, E. A.
Pechen, N. A.
Fukin, G. K.
Cherkasov, A. V.
Faerman, V. I.
Grishina, N. Yu.
RUSSIAN CHEMICAL BULLETIN, 2018, 67 (05) : 884 - 892

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