Synthesis, structure and catalytic activity of new ferrocenyl-containing secondary alcohols derived from l-proline

被引：0
|
作者：
Burlutsky, Roman O. [1 ]
Yudina, Ella S. [1 ]
Churakov, Andrei, V [2 ]
Lemenovskiy, Dmitriy A. [1 ]
Dyadchenko, Victor P. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
[2] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2024年 / 34卷 / 02期
关键词：
asymmetric organocatalysis; ferrocene; proline; benzyloxycarbonyl protective group; ferrocenylmagnesium bromide; chiral secondary alcohols; X-ray molecular structure; enantioselective addition; diethylzinc; ENANTIOSELECTIVE SYNTHESIS; ORGANOCATALYSIS; DERIVATIVES;
D O I：
10.1016/j.mencom.2024.02.013
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New ferrocenyl-containing diastereomeric secondary alcohols derived from L-proline of (ferrocenyl)(pyrrolidin-2-yl)methanol chemotype were synthesized. Their crystal and molecular structure was explored. The prepared chiral secondary and tertiary alcohols in which hydroxy group is sterically hindered by ferrocene substituents show asymmetric induction effect in reaction between diethylzinc and benzaldehyde.
引用
收藏
页码：201 / 203
页数：3
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