Bronze corrosion protection by bilayer systems: Self-assembled monolayers of phosphonic acid/waterborne acrylic coating

被引:4
|
作者
Kapitanovic, Angela [1 ]
Kokot, Tea [1 ]
Curkovic, Helena Otmacic [1 ]
机构
[1] Univ Zagreb, Fac Chem Engn & Technol, Res Lab Corros Engn & Surface Protect, Savska 16, Zagreb HR-10000, Croatia
关键词
Phosphonic acid; Adhesion promoter; Corrosion inhibition; Waterborne coating; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; OCTADECYLPHOSPHONIC ACID; ORGANOPHOSPHONIC ACID; ORGANIC COATINGS; ADHESION; SURFACE; SILANE; POLYMER; GOLD; PERFORMANCE;
D O I
10.1016/j.porgcoat.2023.107984
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The self-assembled monolayers of three long-chain phosphonic acids were investigated as possible adhesion promoters and corrosion inhibitors that could improve the corrosion protection of bronze by an acrylic waterborne coating. Corrosion behaviour was investigated by polarization measurements and electrochemical impedance spectroscopy (EIS) under continuous exposure to simulated acid rain and accelerated aging in a corrosion chamber with NO2. The obtained results showed that all the studied phosphonic acids can improve the protective properties of waterborne coating, but their effect depended on the application method. For adsorption carried out by immersion in an acid solution, the 12-aminododecyl phosphonic acid/coating system showed the best corrosion protection while for the brush application that was 12-phosphonododecylphosphonic acid/coating system. Adhesion measurements showed significant improvement of coating adhesion for 12-aminododecyl phosphonic acid immersion application. The surface wettability investigated by contact angle measurements turned to be a good indicator of the effectiveness of the surface pretreatment.
引用
收藏
页数:11
相关论文
共 50 条
  • [41] Tuning the Work Function of Polar Zinc Oxide Surfaces using Modified Phosphonic Acid Self-Assembled Monolayers
    Lange, Ilja
    Reiter, Sina
    Paetzel, Michael
    Zykov, Anton
    Nefedov, Alexei
    Hildebrandt, Jana
    Hecht, Stefan
    Kowarik, Stefan
    Woell, Christof
    Heimel, Georg
    Neher, Dieter
    ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (44) : 7014 - 7024
  • [42] Formation of Highly Stable Self-Assembled Alkyl Phosphonic Acid Monolayers for the Functionalization of Titanium Surfaces and Protein Patterning
    Han, Xuemingyue
    Sun, Xiangyu
    He, Tao
    Sun, Shuqing
    LANGMUIR, 2015, 31 (01) : 140 - 148
  • [43] Synthesis, characterization, and formation of self-assembled monolayers of a phosphonic acid bearing a vinylene-bridged fluoroalkyl chain
    Shirai, Tomohiro
    Yamauchi, Satoshi
    Kikuchi, Hikari
    Fukumoto, Hiroki
    Tsukada, Hiroto
    Agou, Tomohiro
    APPLIED SURFACE SCIENCE, 2022, 577
  • [44] Multifunctional Aluminum Pre-treatments from End-Functionalized Phosphonic Acid Self-Assembled Monolayers
    Yeo, Reuben J.
    Bleich, Julian N.
    Guerin, Mathilde
    Morganella, Daniela
    Berner, Michele
    Frauenrath, Holger
    LANGMUIR, 2024, 40 (06) : 2872 - 2882
  • [45] PM-IRRAS Determination of Molecular Orientation of Phosphonic Acid Self-Assembled Monolayers on Indium Zinc Oxide
    Sang, Lingzi
    Mudalige, Anoma
    Sigdel, Ajaya K.
    Giordano, Anthony J.
    Marder, Seth R.
    Berry, Joseph J.
    Pemberton, Jeanne E.
    LANGMUIR, 2015, 31 (20) : 5603 - 5613
  • [46] Effect of time and deposition method on quality of phosphonic acid modifier self-assembled monolayers on indium zinc oxide
    Sang, Lingzi
    Knesting, Kristina M.
    Bulusu, Anuradha
    Sigdel, Ajaya K.
    Giordano, Anthony J.
    Marder, Seth R.
    Berry, Joseph J.
    Graham, Samuel
    Ginger, David S.
    Pemberton, Jeanne E.
    APPLIED SURFACE SCIENCE, 2016, 389 : 190 - 198
  • [47] Self-assembled monolayers of alkylphosphonic acid on GaN substrates
    Ito, Takashi
    Forman, Sarah M.
    Cao, Chundi
    Li, Feng
    Eddy, Charles R., Jr.
    Mastro, Michael A.
    Holm, Ronald T.
    Henry, Richard L.
    Hohn, Keith L.
    Edgar, J. H.
    LANGMUIR, 2008, 24 (13) : 6630 - 6635
  • [48] Self-assembled monolayers of octadecanoic acid on indium arsenide
    Knoben, Wout
    Brongersma, Sywert H.
    Crego-Calama, Mercedes
    SURFACE SCIENCE, 2010, 604 (13-14) : 1166 - 1172
  • [49] Corrosion protection of copper by a self-assembled monolayer of alkanethiol
    Feng, YQ
    Teo, WK
    Siow, KS
    Gao, ZQ
    Tan, KL
    Hsieh, AK
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (01) : 55 - 64
  • [50] Cationic systems as self-assembled monolayers on gold surfaces
    Ng, YF
    Strutwolf, J
    Garratt, PJ
    Williams, DE
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 464 (02) : 263 - 267