Constructing Z-scheme g-C3N4/TiO2 heterostructure for promoting degradation of the hazardous dye pollutants

被引:32
|
作者
Vijayan, M. [1 ]
Manikandan, Velu [2 ,3 ,9 ]
Rajkumar, Chellakannu [4 ]
Hatamleh, Ashraf Atef [5 ]
Alnafisi, Bassam Khalid [5 ]
Easwaran, G. [6 ]
Liu, Xinghui [1 ,2 ,8 ]
Sivakumar, K. [7 ]
Kim, Haekyoung [4 ]
机构
[1] Govt Polytech Coll, Dept Chem, Jolarpet 635651, Tamilnadu, India
[2] Yanan Univ, Sch Phys & Elect Informat, Yanan 716000, Peoples R China
[3] Seoul Womens Univ, Dept Food Sci & Technol, 621 Hwarangno, Seoul, South Korea
[4] Yeungnam Univ, Sch Mat Sci & Engn, Gyongsan 38541, South Korea
[5] King Saud Univ, Coll Sci, Dept Bot & Microbiol, PO Box 2455, Riyadh 11451, Saudi Arabia
[6] Govt Polytech Coll, Dept Chem, Dharmapuri 635205, Tamilnadu, India
[7] Adhiyamaan Coll Engn, Dept Chem, Hosur 635109, Tamilnadu, India
[8] Saveetha Sch Engn, Saveetha Inst Med & Tech Sci SIMTS, Dept Mat Phys, Chennai 602105, Tamilnadu, India
[9] Saveetha Dent Coll & Hosp, Saveetha Inst Med & Tech Sci SIMATS, Dept Conservat Dent & Endodont, Chennai 600077, Tamilnadu, India
关键词
Wet impregnation method; Photocatalyst; MB dye; Z-scheme; PHOTOCATALYTIC PERFORMANCE; METHYLENE-BLUE; FABRICATION; NANOFIBERS; COMPOSITE; NANOCOMPOSITES; NANOPARTICLES; ENHANCEMENT; CATALYSTS; H-2;
D O I
10.1016/j.chemosphere.2022.136928
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The use of dyes and segments has increased widely in recent years, but it poses a serious health risk to eco-systems. In this work, TiO2 and two-dimensional g-C3N4 nanosheets (g-CN) were fabricated through co -precipitation and thermal polymerization technique, respectively. The g-CN-TiO2 photocatalyst (1: 3, 2: 2, 3: 1) in various weight percentages was prepared using a simple impregnation process. The photocatalytic behaviour of the g-CN, TiO2 NPs, and different weight percentages of g-CN-TiO2 photocatalyst was evaluated against methylene blue (MB) dye under UV-visible light illumination. Compared to pristine and other weight percentages of the g-CN-TiO2 nanocomposite, the optimized g-CN-TiO2 nanocomposite (3:1) showed promoted performance against MB dye. The enriched catalytic efficiency can be accredited to the low amount of TiO2 nanoparticles deposited on gCN nanosheets, possibly due to the boosted transport properties of the electron-hole pairs. The enriched photocatalytic behaviour can be attributed to the development of the Z-scheme system be-tween TiO2 and g-CN. The current study is an outstanding demonstration of the development of maximum catalytic efficiency for destroying hazardous chemical dyes.
引用
收藏
页数:11
相关论文
共 50 条
  • [1] A new understanding of the photocatalytic mechanism of the direct Z-scheme g-C3N4/TiO2 heterostructure
    Liu, Jianjun
    Cheng, Bei
    Yu, Jiaguo
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (45) : 31175 - 31183
  • [2] Z-Scheme TiO2/g-C3N4 Activation of Peroxymonosulfate to Remove Organic Pollutants: Properties and Mechanism
    Zhang, Yujie
    Ren, Xuechang
    Yang, Linhai
    Wang, Huijuan
    Chen, Juxiang
    Li, Jinhui
    Wang, Rong
    [J]. CHEMISTRYSELECT, 2023, 8 (27):
  • [3] Mechanistic insight into photocatalytic CO2 reduction by a Z-scheme g-C3N4/TiO2 heterostructure
    Wang, Shuo
    Zhao, Tingting
    Tian, Yu
    Yan, Likai
    Su, Zhongmin
    [J]. NEW JOURNAL OF CHEMISTRY, 2021, 45 (26) : 11474 - 11480
  • [4] Construction of direct Z-scheme g-C3N4/TiO2 nanorod composites for promoting photocatalytic activity
    Liu, Mei
    Wei, Shaojie
    Chen, Wei
    Gao, Li
    Li, Xiying
    Mao, Liqun
    Dang, Haifeng
    [J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2020, 67 (02) : 246 - 252
  • [5] Influence of TiO2 morphology on the photocatalytic efficiency of direct Z-scheme g-C3N4/TiO2 photocatalysts for isoniazid degradation
    Jo, Wan-Kuen
    Natarajan, Thillai Sivakumar
    [J]. CHEMICAL ENGINEERING JOURNAL, 2015, 281 : 549 - 565
  • [6] Z-Scheme versus type-II junction in g-C3N4/TiO2 and g-C3N4/SrTiO3/TiO2 heterostructures
    Di Liberto, Giovanni
    Tosoni, Sergio
    Pacchioni, Gianfranco
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2021, 11 (10) : 3589 - 3598
  • [7] Enhanced photocatalytic performance of Z-scheme TiO2/g-C3N4 heterojunction towards degradation of Rhodamine B
    Yang, Y.
    Wang, D. Y.
    Zhang, Y. C.
    Chen, S. Y.
    Sun, Y.
    [J]. DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 2022, 17 (04) : 1491 - 1500
  • [8] Synthesis of MoS2 nanosheet supported Z-scheme TiO2/g-C3N4 photocatalysts for the enhanced photocatalytic degradation of organic water pollutants
    Jo, Wan-Kuen
    Adinaveen, T.
    Vijaya, J. Judith
    Selvam, N. Clament Sagaya
    [J]. RSC ADVANCES, 2016, 6 (13) : 10487 - 10497
  • [9] g-C3N4 based Z-scheme photocatalysts for environmental pollutants removal
    Bairamis, Feidias
    Rapti, Ilaeira
    Konstantinou, Ioannis
    [J]. CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY, 2023, 40
  • [10] Supramolecule self-assembly approach to direct Z-scheme TiO2/g-C3N4 heterojunctions for efficient photocatalytic degradation of emerging phenolic pollutants
    Liu, Yunqing
    Ren, Miao
    Zhang, Xueyan
    Yang, Guang
    Qin, Lang
    Meng, Jiaqi
    Guo, Yihang
    [J]. APPLIED SURFACE SCIENCE, 2022, 593