Ligand-assisted formation of mesoporous Zn-N-C to realize superior catalytic activity in solvent-free CO2 cycloaddition reactions

被引：1
|
作者：
Zhou, Yan [1 ,2 ]
Lv, Shanshan [2 ]
Feng, Mengmeng [2 ]
Qian, Changjin [2 ]
Liu, Shoujie [1 ]
Chen, Zheng [2 ,3 ]
机构：
[1] Anhui Univ, Sch Mat Sci & Engn, Hefei 230601, Peoples R China
[2] Anhui Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Mol Solids, Minist Educ, Wuhu 241002, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210023, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 19期
关键词：
DOPED CARBON; EFFICIENT; PERFORMANCE; FRAMEWORK; SITES;
D O I：
10.1039/d4cc00171k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mesoporous nitrogen-doped carbon-anchored single atom Zn was synthesized through etching of ZIF-8 with 1,10-phenanthroline and subsequent pyrolysis based on the Kirkendall effect. The abundant pores and increased surface area promote CO2 adsorption and mass transfer, thus significantly improving the catalytic activity in solvent-free cycloaddition of epoxides with CO2.
引用
收藏
页码：2641 / 2644
页数：4
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