The influence of Au2O3 on insulating character of ZnO-P2O5-SeO2 glass system: investigation by means of dielectric studies

被引:3
|
作者
Reddy, G. Naga Koti [1 ]
Sekhar, A. Venkata [1 ]
Pavic, L. [2 ]
Bafti, A. [3 ]
Pisk, Jana [4 ]
Reddy, A. Siva Sesha [5 ]
Venkatramaiah, N. [6 ]
Raju, G. Naga [1 ]
Kumar, V. Ravi [1 ]
Veeraiah, N. [1 ,7 ]
机构
[1] Acharya Nagarjuna Univ, Dept Phys, Guntur 522510, India
[2] Rudjer Boskovic Inst, Zagreb 10000, Croatia
[3] Univ Zagreb, Fac Chem Engn & Technol, Zagreb 10000, Croatia
[4] Univ Zagreb, Fac Sci, Dept Chem, Zagreb 10000, Croatia
[5] Krishna Univ, Dept Phys, Machilipatnam 521004, Andhra Pradesh, India
[6] SRM Inst Sci & Technol, Dept Chem, Chennai, India
[7] Andhra Loyola Coll Autonomous, Dept Phys, Vijayawada, Andhra Pradesh, India
来源
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING | 2023年 / 129卷 / 03期
关键词
ZnO-P2O5-SeO2; glasses; Au ions; Dielectric studies; A; C; conductivity; Dielectric breakdown strength; OPTICAL-PROPERTIES; DOPED ZNO; FEATURES; CONDUCTIVITY; DISPERSION; CERAMICS; BEHAVIOR; FILMS; OXIDE;
D O I
10.1007/s00339-023-06422-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Zinc selenium phosphate glasses added with the traces of Au2O3 were prepared and heat-treated. XRD, TEM, DSC, FT-IR and optical absorption (OA) spectroscopy methods were used for the structural assessment of these samples. Later, different dielectric parameters viz., dielectric constant (epsilon '), electric moduli (M), impedance (Z) and a.c. conductivity (sigma(ac)) were measured over wide regions of frequency (omega) and temperature (T) as functions of Au2O3 concentration. Dielectric breakdown strength (DBS) of these samples was also measured at ambient conditions. The characterization studies indicated that multiple crystal grains were entrenched in the residual amorphous phase of the samples. The X-ray diffraction studies revealed that the bulk glasses consisted of Au-2(SeO3)(3) crystal phase and Au-0 metallic particles (MPs). As Au2O3 content was raised, the intensity of the XRD peak related to Au3+ crystal phase indicated a growing trend, whereas that of Au-0 MPs showed a decreasing trend. The results of XPS studies revealed similar inferences. The FT-IR results pointed out an improved degree of augmentation of the glass network as the content of Au2O3 was increased. Optical absorption (OA) - spectra of the glasses indicated a broad absorption band in the spectral range of 500-600 nm due to the surface plasmon resonance (SPR) of Au-0 MPs. The intensity of the band was observed to decrease as Au2O3 content was increased and indicated decreasing proportion of Au-0 metallic particles in the samples. The dielectric parameters exhibited a decreasing trend, whereas the dielectric breakdown strength (DBS) and electrical impedance indicated a substantial hike due to the increasing concentration of Au2O3. Overall, the presence of Au2O3 caused a significant improvement in the insulating strength of the ZnO added SeO2-P2O5 glasses and hence such glasses may be considered as insulating layers in the display panel devices.
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页数:16
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