The 2,8-Dibromo-6H,12H-6,12-epoxydibenzo[b,f][1,5]dioxocine

被引:0
|
作者
Aitken, R. Alan [1 ]
Cordes, David B. [1 ]
Ler, An Jie [1 ]
Mckay, Aidan P. [1 ]
机构
[1] Univ St Andrews, EaStCHEM Sch Chem, North Haugh KY16 9ST, Fife, Scotland
关键词
X-ray structure; disalicylaldehyde; trioxabicyclo[3.3.1]nonadiene;
D O I
10.3390/M1729
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The title dibromodisalicylaldehyde, obtained as a by-product in the m-chloroperoxybenzoic acid oxidation of 5-bromo-2-(methoxymethoxy)benzaldehyde, has been characterised by IR and NMR spectroscopy and X-ray diffraction. The structure features two independent molecules with a pi-pi stacking interaction between them.
引用
收藏
页数:5
相关论文
共 50 条
  • [21] General protocols for the synthesis of C2-symmetric and asymmetric 2,8-disubstituted analogues of Troger's base via efficient bromine-lithium exchanges of 2,8-dibromo-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine
    Jensen, J
    Tejler, J
    Wärnmark, K
    JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (17): : 6008 - 6014
  • [22] Diethyl 4,10-dibromo-5,11-methano-6H, 12H-dibenzo[b,f][1,5]diazocine-2,8-dicarboxylate
    Bhuiyan, M. Delower H.
    Try, Andrew C.
    Klepetko, John
    Turner, Peter
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O4887 - O4888
  • [23] 2,8-Dimethyl-1,9-dinitro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine
    Bhuiyan, M. Delower H.
    Jensen, Paul
    Try, Andrew C.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O908 - O909
  • [24] TRANSITION-METAL COMPLEXES OF 2,8-DIMETHYL-6H, 12 H-5, 11-METHANODIBENZO [B,F] [1,5] DIAZOCINE
    SAEEDURRAHMAN
    JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 1987, 9 (04): : 503 - 514
  • [25] Dimethyl 6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine-2,8-dicarboxylate
    Faroughi, Masoud
    Try, Andrew C.
    Turner, Peter
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O3479 - O3480
  • [26] 5,11-Dimethyldibenzo[b,f][1,5]diazocine-6,12(5H,11H)-dione
    Mahon, Andrew B.
    Jensen, Paul
    Try, Andrew C.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O469 - U2560
  • [27] Dimethyl 6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine-2,8-diacetate
    Faroughi, Masoud
    Jensen, Paul
    Try, Andrew C.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O500 - U2823
  • [28] STRUCTURE OF 5,11-BIS(CHLOROFORMYL)-2,8-DIMETHYL-6H,12H-DIBENZO[B,F][1,5]DIAZOCINE AT 163 K
    LARSON, SB
    WILCOX, CS
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 : 376 - 378
  • [29] 6,12-DIPHENYLDIBENZO[B,F][1,5]DIAZOCINES
    METLESIC.W
    RESNICK, T
    SILVERMA.G
    TAVARES, R
    STERNBAC.LH
    JOURNAL OF MEDICINAL CHEMISTRY, 1966, 9 (04) : 633 - &
  • [30] Efficient synthesis of dialkyl (2E)-2-(6H,12H-6,12-epiminodibenzo[b, f][1,5]dioxocin-13-yl)but-2-enedioates via a pseudo four-component reaction
    Wang, Ting
    Qian, Siran
    Qing, Xushun
    Wang, Cunde
    JOURNAL OF CHEMICAL RESEARCH, 2017, (10) : 603 - 607