Copper triazole complex supported on Fe3O4@SiO2 nanoparticles as eco-friendly nanocatalysts in solvent-free Biginelli reaction

被引：4
|
作者：
Mekki, Sofiane [1 ,2 ]
Laichi, Yacine [3 ]
Benourrad, Farouk [1 ]
Lagha, Narimen [1 ]
Chebout, Redouane
Bachari, Khaldoun [3 ]
Saidi-Besbes, Salima [1 ]
机构：
[1] Univ Oran 1, Dept Chim, Lab Synth Organ Appl LSOA, BP 1524, El Mnaouer 31000, Oran, Algeria
[2] Ecole Super Genie Elect & Energet Oran, BP 64 CH2 Achaba Hanifi USTO, Oran 31000, Algeria
[3] Ctr Rech Sci & Tech Anal Phys Chim CRAPC, BP 384, Bou Ismail 42004, Algeria
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2023年 / 37卷 / 08期
关键词：
Biginelli reaction; ecofriendly chemistry; heterogeneous catalyst; magnetic nanoparticles; one-pot reaction; IONIC LIQUID; CATALYST; DERIVATIVES; ANALOGS; PH;
D O I：
10.1002/aoc.7103
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
In this work, a new heterogeneous catalyst based on 1,2,3-triazole complex of copper supported on core-shell Fe3O4@SiO2 nanoparticles was designed and characterized by using several methods such as infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetry analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and energy-dispersive X-ray spectroscopy (EDX). The magnetic nanocatalyst was successfully employed for the synthesis of different functionalized 3,4-dihydropyrimidin-2(1H)-ones/thiones by a one-pot multicomponent condensation reaction under solvent-free conditions. Among the advantages of the developed catalytic protocol are the high yields, short reaction times, ecofriendly, easy workup and purification conditions.
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收藏
页数：12
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