Incorporation of Magnetic Filler (Co0.2Zn0.2Cd0.6Fe2O4) in PVA Matrix and Studying the Structural, Optical and Mechanical Properties of Nanocomposite Films

被引:10
|
作者
Mostafa, M. [1 ]
Abdelhakim, Nermin A. [2 ]
Hemeda, O. M. [1 ]
Shalaby, Rizk M. [2 ]
Salem, B. I. [1 ]
机构
[1] Tanta Univ, Fac Sci, Phys Dept, Tanta 31527, Egypt
[2] Mansoura Univ, Fac Sci, Phys Dept, Mansoura 35516, Egypt
关键词
PVA; UV-Vis spectroscopy; SELF; VELF; Vickers hardness; Stress exponent; POLY(VINYL ALCOHOL) NANOCOMPOSITES; POLYVINYL-ALCOHOL; POLYMER NANOCOMPOSITES; NANOINDENTATION CREEP; ELECTRICAL-PROPERTIES; OXIDE NANOPARTICLES; SINGLE-CRYSTAL; BAND-GAP; CONSTANTS; SILICA;
D O I
10.1007/s10904-024-03045-z
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The goal of this study is to synthesize nanocomposite PVA/ Co0.2Zn0.2Cd0.6Fe2O4 films with varying contents of Co0.2Zn0.2Cd0.6Fe2O4 nanoparticles (x = 0, 0.2, 0.4, 0.6, 0.8) to improve the structural, optical, and mechanical characteristics of the examined materials. Casting technique is used to prepare PVA/ Co0.2Zn0.2Cd0.6Fe2O4 films. X-ray diffraction, FTIR, UV-Vis spectroscopy, and Vickers Hardness were used to examine the effect of magnetic nanoparticle content on the structural, optical, and mechanical characteristics of PVA nanocomposite films. The refractive index rises from 1.4967 for pure PVA to 7.6511 for PVA + 0.8Co(0.2)Zn(0.2)Cd(0.6)Fe(2)O(4), allowing it to be employed in a variety of applications such as solar cell construction. Because of the presence of ferrite in the glass matrix, the average hardness values enhanced and increased from 90.7 to 114.2 MPa. The stress exponent (n) varies from 1.12 to 3.33, with grain boundary sliding as the deformation mechanism for x = 0, viscous glid for x = 0.2, 0.4, and 0.6, and dislocation climb for x = 0.8 nanocomposite thin films.
引用
收藏
页码:3736 / 3753
页数:18
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