Zn2SnO4/SnO2/g-C3N4 heterojunction: High efficiency photocatalytic degradation of Rhodamine B in simulated visible light

被引:11
|
作者
Zhang, Yangrui [1 ]
Zhang, Haiyang [1 ]
Deng, Renpan [1 ]
Cheng, Yikun [1 ]
Wu, Yuhao [1 ]
Zhang, Jinli [1 ]
机构
[1] Shihezi Univ, Sch Chem & Chem Engn, State Key Lab Incubat Base Green Proc Chem Engn, Shihezi 832003, Peoples R China
基金
中国国家自然科学基金;
关键词
g-C3N4; Zn2SnO4; SnO2; Heterojunction; Photocatalysis; HYDROTHERMAL SYNTHESIS; G-C3N4; NANOSHEETS; COMPOSITE; ZN2SNO4; HETEROSTRUCTURES; NANOPARTICLES; CONSTRUCTION; FABRICATION; PERFORMANCE; BI2WO6;
D O I
10.1016/j.ces.2023.119551
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Photocatalysis is an effective solution to wastewater treatment problems, and semiconductor heterojunctions for photocatalysis can effectively separate photogenerated carriers to improve the performance of photocatalytic degradation of pollutants. In this paper, a ternary composite photocatalyst with a heterojunction structure (Zn2SnO4/SnO2/g-C3N4) was prepared to photodegrade Rhodamine B in simulated visible light. The experimental findings demonstrate that the Zn2SnO4/SnO2/g-C3N4 photodegradation rates and efficiencies for RhB are much higher than those for SnO2, g-C3N4, SnO2/g-C3N4, and Zn2SnO4/SnO2. We obtained a 3:1 mass ratio of Zn2SnO4/SnO2 to g-C3N4 by optimization, with a maximum degradation rate of 99.5 % and a maximum kinetic constant k of 0.692 min(-1)center dot g(-1) for the photocatalytic removal of RhB by Zn2SnO4/SnO2/g-C3N4. The radical trapping experiments suggest the primary role of center dot O-2(-) for the photocatalytic removal of RhB. The ternary composite photocatalyst Zn2SnO4/SnO2/g-C3N4 shows promise for potential applications in RhB degradation owing to its exceptionally.
引用
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页数:10
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