Green Synthesis of MIL-88B(Cr) with the Co-Modulator of Nitric Acid and Acetic Acid

被引：2
|
作者：
Li, Fuzhi [1 ]
Tang, Songfan [1 ]
Li, Mingmin [1 ]
Xiao, Pengcheng [1 ]
Luo, Mingliang [1 ]
Zhao, Tian [1 ]
机构：
[1] Hunan Univ Technol, Sch Packaging & Mat Engn, Zhuzhou 412007, Peoples R China
来源：
INORGANICS | 2023年 / 11卷 / 07期
基金：
中国国家自然科学基金;
关键词：
MIL-88B(Cr); flexible Cr-based MOF; co-modulator; green synthesis; METAL-ORGANIC-FRAMEWORKS; ADSORPTION; DELIVERY;
D O I：
10.3390/inorganics11070292
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
MIL-88B(Cr) is a prototypical flexible chromium-based metal-organic framework (MOF), which possesses extremely strong water/thermal stability and excellent "swelling/breathing" ability. However, in previous studies, there have been very few reports on MIL-88B(Cr) due to unclear synthesis details. Here, we found that the pure MIL-88B(Cr) can be facile synthesized through a hydrothermal method with the co-use of nitric acid and acetic acid (molar ratio = 1:15). The obtained MIL-88B(Cr) was sufficiently characterized by diverse techniques to assure its high-level quality. This work emphasizes a future valuable approach to expanding the production of flexible Cr-based MOF.
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页数：8
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