Plasticized green electrolyte and table salt for energy storage applications

被引:1
|
作者
Hamsan, Muhamad H. [1 ]
Aziz, Shujahadeen B. [2 ,3 ]
Abdulwahid, Rebar T. [4 ,5 ]
Brza, Mohamad A. [3 ]
Halim, Norhana Abdul [6 ]
Abdalrahman, Ari A. [2 ]
Al-Saeedi, Sameerah I. [7 ]
Kadir, Mohd F. Z. [8 ,9 ]
Aziz, Dara M. [10 ]
机构
[1] Univ Kebangsaan Malaysia, Pusat Pengajian Citra Univ, Jalan Temuan, Bangi 43600, Selangor, Malaysia
[2] Univ Sulaimani, Res & Dev Ctr, Hameed Majid Adv Polymer Mat Res Lab, Sulaymaniyah 46001, Iraq
[3] Charmo Univ, Coll Sci, Dept Phys, Sulaymaniyah 46023, Iraq
[4] Cihan Univ Sulaimaniya, Coll Hlth Sci, Med Lab Anal Dept, Sulaimaniya 46001, Kurdistan Regio, Iraq
[5] Univ Sulaimani, Coll Educ, Dept Phys, Old Campus, Sulaymaniyah 46001, Kurdistan Regio, Iraq
[6] Natl Def Univ Malaysia, Ctr Def Fdn Studies, Dept Phys, Sungai Besi Camp, Kuala Lumpur 57000, Malaysia
[7] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Dept Chem, POB 84428, Riyadh 11671, Saudi Arabia
[8] Univ Malaya, Fac Sci, Dept Phys, Kuala Lumpur 50603, Malaysia
[9] Univ Malaya, Ctr Ion Liquids UMCiL, Kuala Lumpur 50603, Malaysia
[10] Univ Raparin, Coll Sci, Dept Chem, Ranya 46012, Kurdistan Regio, Iraq
关键词
GEL POLYMER ELECTROLYTE; IONIC LIQUID; ELECTRICAL-PROPERTIES; DIELECTRIC-PROPERTIES; HIGH-PERFORMANCE; CHITOSAN; CONDUCTIVITY; LITHIUM; PEO; POLYANILINE;
D O I
10.1007/s10853-023-08895-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The main purpose of this research is to construct an energy storage device using green solid polymer electrolyte and nontoxic salt, due to the rising number of microplastics in the ocean that can affect our health. Activated carbon materials were used to fabricate symmetrical electrodes. A SPE system was fabricated by solution casting with chitosan (CS) and dextran as the polymer host to accommodate sodium chloride (NaCl salt) for the ionic transport process. The maximum conductivity displayed by the CSDNCG4 system is 1.09 x 10-4 S/cm. The system exhibits non-Debye behavior, as evidenced by the depressed semicircle with its diameter below the real-axis and an asymmetrical tan delta. The plasticizer boosts the ion transport parameters. Various dielectric characteristics, including dielectric loss, electric modulus and dielectric constant, are measured versus frequency. Dielectric analysis and conductivity show the same trend. Through TNM measurement, the ion fraction and its contribution were identified. The potential stability of the CS/dextran/NaCl film was found to reach 1.8 V. The capacitive behavior of the constructed EDLC was analyzed using the CV test. The Cspe was found to be 7.3 F/g at 10 mV/s.
引用
收藏
页码:14121 / 14139
页数:19
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