Synthesis, crystal structures and electrocatalytic properties of 2D and 3D Co(II) Coordination polymers based on semi-rigid tricarboxylic acid ligand

被引：1
|
作者：
Liang, Guang-Ming [1 ,3 ]
Xiang, Zeng-Ni [1 ]
Yang, Jie [1 ]
Xian, Zhong-Mei [1 ]
Song, Guo-Long [1 ]
Wu, Ling [1 ]
Xu, Mei-Yu [1 ]
Wang, Xiu-Jian [2 ]
Xiong, Peng [2 ]
机构：
[1] China West Normal Univ, Coll Chem & Chem Engn, Chem Synth & Pollut Control Key Lab Sichuan Prov, Nanchong 637002, Peoples R China
[2] Guangxi Normal Univ, Sch Chem & Pharmaceut Sci, Guilin 541004, Peoples R China
[3] Sichuan Univ Sci & Engn, Innovat Ctr Chenguang High Performance Fluorine Ma, Zigong, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2023年 / 1284卷
关键词：
CPs; Topology; Crystal structures; Electrocatalyst; METAL-ORGANIC FRAMEWORK; OXYGEN EVOLUTION;
D O I：
10.1016/j.molstruc.2023.135371
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The tricarboxylic ligand, 4',4',4'-[(trimethylamino)]-tris[(1,1'-biphenyl)-2-carboxylic acid] (H3TMCA), is designed and synthesized to self-assembly two novel cobalt coordination polymers, formulated as {[Co2(TMCA)(OH)(DMF)(H2O)]}n (1), {[Co3(TMCA)2]}n (2). Interesting, due to the flexibility of the H3TMCA, the final frameworks of 1-2 can change depending on the reaction of temperature and solvents. Com-plex 1 is a (3, 6)-connected of type kgd two-dimensional (2D) network with a point (Schlafli) symbol of {43 }2{46. 66. 83 }. Complex 2 is a (4, 6)-connected 2-nodal three-dimensional (3D) net with point (Schlafli) symbol of {415 }2{42. 84 }3. In addition, the electrocatalytic activity of these Co-CPs were studied in detail.(c) 2023 Elsevier B.V. All rights reserved.
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页数：7
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