Field-Stepwise-Swept Solid-State 35Cl NMR and NQR of trichloroisocyanuric acid

被引：0

作者：

Yamada, Kazuhiko ^{[1
]}

Takahashi, Masato ^{[2
]}

Tritrakarn, Techit ^{[3
]}

Okamura, Tetsuji ^{[3
]}

机构：

[1] Kochi Univ, Res & Educ Fac, Interdisciplinary Sci Unit, Multidisciplinary Sci Cluster, Oko Campus, Nankoku, Kochi 7838505, Japan

[2] Ctr Biosyst Dynam Res, Lab NMR Engn & Struct Sci, RIKEN Yokohama Campus, Kanagawa 2300045, Japan

[3] Tokyo Inst Technol, Dept Mech Engn, 4259 Nagatusta cho,Midori ku, Yokohama, Kanagawa 2268502, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2023年 / 811卷

关键词：

Field-stepwise-swept solid-state NMR; NQR; Cl-35; Trichloroisocyanuric acid; SPECTROSCOPY; SPECTRA; ACQUISITION; CHLORINE;

D O I：

10.1016/j.cplett.2022.140250

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Field-stepwise-swept solid-state 35Cl nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) experiments of trichloroisocyanuric acid (TCICA) are carried out. The quadrupolar frequencies, vQ, were found to be 57.9 - 58.8 MHz in the temperature range between 180 and 299 K. The analysis of the field-stepwise -swept solid-state 35Cl NMR spectrum, observed at 240 K and acquired at 43.25 MHz, yields the quadrupolar coupling constant (CQ) of 116.6(2) MHz and the asymmetric parameter (eta Q) of 0.05(5). The tensor orientation of the 35Cl Electric-Field-Gradient (EFG) tensor is briefly discussed.

引用

页数：4

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