A digital baffle batch reactor (DBBR) for oxidative desulfurization (ODS) reactions is designed and applied here to reduce the sulfur concentration presented in light gas oil (LGO) based on a novel homemade nano-catalyst (Copper Oxide (CuO)/Activated Carbon (AC)). With efficient impregnation, good pore size distribution, high activity, and higher surface area, the designed nanocatalyst (CuO/AC) demonstrated excellent catalytic efficiency. To evaluate the effectiveness of nanocatalyst (prepared experimentally), several experiments related to ODS reactions using the digital baffle batch reactor are carried out under moderate process conditions (reaction temperature (100, 120 and 140 degrees C), contact time (15, 30, and 45 min) and oxidant (H2O2) amount (2, 3 and 5 mL)). The experimental outcomes indicated that increasing the reaction temperature, batch time, and oxidant amount led to the reduced sulfur concentration of oil feedstock leading to a greener fuel. The efficiency of sulfur conversion is reported to be 83.1 % using the modified nano-catalysts and new reactor (DBBR) at reaction temperature 140 C-o, batch time 45 min, and H(2)O(2 )amount of 5 mL. So, such new results using DBBR for ODS reactions based on CuO/AC as a new modified nanocatalyst have not been reported in the public domain and it is considered new results.
机构:
King Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
King Fahd Univ Petr & Minerals, Ctr Excellence Nanotechnol, Dhahran 31261, Saudi ArabiaKing Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
Gondal, M. A.
Ilyas, A. M.
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King Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
King Fahd Univ Petr & Minerals, Ctr Excellence Nanotechnol, Dhahran 31261, Saudi ArabiaKing Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
Ilyas, A. M.
Fasasi, T. A.
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King Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
King Fahd Univ Petr & Minerals, Ctr Excellence Nanotechnol, Dhahran 31261, Saudi ArabiaKing Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
Fasasi, T. A.
Dastageer, M. A.
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King Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
King Fahd Univ Petr & Minerals, Ctr Excellence Nanotechnol, Dhahran 31261, Saudi ArabiaKing Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
Dastageer, M. A.
Seddigi, Z. S.
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机构:
Umm Al Qura Univ, Dept Environm Hlth, Fac Publ Hlth & Hlth Informat, Mecca 21955, Saudi ArabiaKing Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
Seddigi, Z. S.
Qahtan, T. F.
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King Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
King Fahd Univ Petr & Minerals, Ctr Excellence Nanotechnol, Dhahran 31261, Saudi ArabiaKing Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
Qahtan, T. F.
Faiz, M.
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King Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
King Fahd Univ Petr & Minerals, Ctr Excellence Nanotechnol, Dhahran 31261, Saudi ArabiaKing Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
Faiz, M.
Khattak, G. D.
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King Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
King Fahd Univ Petr & Minerals, Ctr Excellence Nanotechnol, Dhahran 31261, Saudi ArabiaKing Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
机构:
Iran Polymer & Petrochem Inst, Fac Petrochem, POB 14975-112, Tehran 1497713115, IranIran Polymer & Petrochem Inst, Fac Petrochem, POB 14975-112, Tehran 1497713115, Iran
Ghashghaee, Mohammad
Shirvani, Samira
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Iran Polymer & Petrochem Inst, Fac Petrochem, POB 14975-112, Tehran 1497713115, Iran
Univ British Columbia, Dept Chem & Biol Engn, 2360 East Mall, Vancouver, BC V6T 1Z3, CanadaIran Polymer & Petrochem Inst, Fac Petrochem, POB 14975-112, Tehran 1497713115, Iran
Shirvani, Samira
Ghambarian, Mehdi
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机构:
Iran Polymer & Petrochem Inst, Gas Convers Dept, Fac Petrochem, POB 14975-112, Tehran 1497713115, IranIran Polymer & Petrochem Inst, Fac Petrochem, POB 14975-112, Tehran 1497713115, Iran
Ghambarian, Mehdi
Kegnaes, Soren
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机构:
Tech Univ Denmark, Dept Chem, DK-2800 Lyngby, DenmarkIran Polymer & Petrochem Inst, Fac Petrochem, POB 14975-112, Tehran 1497713115, Iran
机构:
Minist Higher Educ & Sci Res, Res Ctr Ind Technol CRTI, POB 64, Algiers 16014, AlgeriaUniv 20 August 1955, Lab Physicochem Res Surfaces & Interfaces LRPCSI, Skikda 21000, Algeria
Haddad, Ahmed
Gouasmia, Abir
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Univ 20 August 1955, Lab Physicochem Res Surfaces & Interfaces LRPCSI, Skikda 21000, Algeria
Univ 20 August 1955, Fac Technol, Dept Proc Engn, Skikda 21000, AlgeriaUniv 20 August 1955, Lab Physicochem Res Surfaces & Interfaces LRPCSI, Skikda 21000, Algeria
Gouasmia, Abir
Avramova, Ivalina
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Bulgarian Acad Sci, Inst Gen & Inorgan Chem, Block 11,Acad G Bonchev Str, Sofia 1113, BulgariaUniv 20 August 1955, Lab Physicochem Res Surfaces & Interfaces LRPCSI, Skikda 21000, Algeria
Avramova, Ivalina
Mohammed, Zighed
论文数: 0引用数: 0
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机构:
MHamed Bougara Univ, Fac Technol, Res Unit Mat Proc & Environm URMPE, Boumerdes, AlgeriaUniv 20 August 1955, Lab Physicochem Res Surfaces & Interfaces LRPCSI, Skikda 21000, Algeria
Mohammed, Zighed
Parvulescu, Vasile I.
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Univ Bucharest, Fac Chem, Dept Organ Chem Biochem & Catalysis, Bdul Regina Elisabeta 4-12, Bucharest 030016, RomaniaUniv 20 August 1955, Lab Physicochem Res Surfaces & Interfaces LRPCSI, Skikda 21000, Algeria
Parvulescu, Vasile I.
Yadav, Krishna Kumar
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机构:
Madhyanchal Profess Univ, Fac Sci & Technol, Bhopal 462044, India
Al Ayen Univ, Sci Res Ctr, Environm & Atmospher Sci Res Grp, Nasiriyah 64001, Thi Qar, IraqUniv 20 August 1955, Lab Physicochem Res Surfaces & Interfaces LRPCSI, Skikda 21000, Algeria
Yadav, Krishna Kumar
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Hasan, Mudassir
Cabral-Pinto, Marina M. S.
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机构:
Univ Aveiro, Geobiotec Res Ctr, Dept Geosci, P-3810193 Aveiro, PortugalUniv 20 August 1955, Lab Physicochem Res Surfaces & Interfaces LRPCSI, Skikda 21000, Algeria
Cabral-Pinto, Marina M. S.
Elboughdiri, Noureddine
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机构:
Univ Hail, Coll Engn, Chem Engn Dept, POB 2440, Hail 81441, Saudi Arabia
Univ Gabes, Chem Proc Engn Dept, Natl Sch Engineers Gabes, Gabes 6029, TunisiaUniv 20 August 1955, Lab Physicochem Res Surfaces & Interfaces LRPCSI, Skikda 21000, Algeria
Elboughdiri, Noureddine
Benguerba, Yacine
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机构:
Univ Hail, Coll Engn, Chem Engn Dept, POB 2440, Hail 81441, Saudi Arabia
Ferhat Abbas Set 1 Univ, Lab Biopharm & Pharmacotech LPBT, Setif, AlgeriaUniv 20 August 1955, Lab Physicochem Res Surfaces & Interfaces LRPCSI, Skikda 21000, Algeria
机构:
Univ Putra Malaysia, Fac Sci, Catalysis Sci & Technol Res Ctr, Upm Serdang 43400, Selangor, Malaysia
Univ Putra Malaysia, Fac Sci, Dept Chem, Upm Serdang 43400, Selangor, MalaysiaUniv Putra Malaysia, Fac Sci, Catalysis Sci & Technol Res Ctr, Upm Serdang 43400, Selangor, Malaysia
Abdulkareem-Alsultan, G.
Asikin-Mijan, N.
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Univ Putra Malaysia, Fac Sci, Catalysis Sci & Technol Res Ctr, Upm Serdang 43400, Selangor, Malaysia
Univ Malaya, Inst Postgrad Studies, Nanotechnol & Catalysis Res Ctr, Kuala Lumpur 50603, MalaysiaUniv Putra Malaysia, Fac Sci, Catalysis Sci & Technol Res Ctr, Upm Serdang 43400, Selangor, Malaysia
Asikin-Mijan, N.
Mansir, Nasar
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Univ Putra Malaysia, Fac Sci, Catalysis Sci & Technol Res Ctr, Upm Serdang 43400, Selangor, Malaysia
Univ Putra Malaysia, Fac Sci, Dept Chem, Upm Serdang 43400, Selangor, Malaysia
Fed Univ, Dept Chem, Dutse 7156, Jigawa State, NigeriaUniv Putra Malaysia, Fac Sci, Catalysis Sci & Technol Res Ctr, Upm Serdang 43400, Selangor, Malaysia
Mansir, Nasar
Lee, H., V
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Univ Malaya, Inst Postgrad Studies, Nanotechnol & Catalysis Res Ctr, Kuala Lumpur 50603, MalaysiaUniv Putra Malaysia, Fac Sci, Catalysis Sci & Technol Res Ctr, Upm Serdang 43400, Selangor, Malaysia
Lee, H., V
Zainal, Zulkarnain
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Univ Putra Malaysia, Fac Sci, Dept Chem, Upm Serdang 43400, Selangor, MalaysiaUniv Putra Malaysia, Fac Sci, Catalysis Sci & Technol Res Ctr, Upm Serdang 43400, Selangor, Malaysia
Zainal, Zulkarnain
Islam, Aminul
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Jessore Univ Sci & Technol, Jessore Sadar, BangladeshUniv Putra Malaysia, Fac Sci, Catalysis Sci & Technol Res Ctr, Upm Serdang 43400, Selangor, Malaysia