Metallogenic mechanism of cobalt in the Zhuchong cobalt -rich skarn iron deposit in the Middle -Lower Yangtze River Valley Metallogenic Belt: Constrained by in -situ sulfur isotopes and zircon U-Pb dating

被引:3
|
作者
Liang Xian [1 ,2 ]
Wang FangYue [1 ,2 ]
Zhou TaoFa [1 ,2 ]
Wei ChangShuai [3 ]
Zhang Long [1 ,2 ]
Guo XianZheng [1 ,2 ]
Zhang Kun [4 ]
机构
[1] Hefei Univ Technol, Sch Resources & Environm Engn, Ore Deposit & Explorat Ctr ODEC, Hefei 230009, Peoples R China
[2] Anhui Prov Engn Res Ctr Mineral Resources & Mine, Hefei 230009, Peoples R China
[3] Bur Geol & Mineral Resources Explorat Anhui Prov, 326 Geol Party, Anqing 246003, Peoples R China
[4] Chinese Acad Geol Sci, Beijing 100037, Peoples R China
关键词
Zhuchong Co -Fe deposit; Middle -Lower Yangtze River Valley Metallogenic Belt; Zircon U-Pb dating; Sulfur isotope; Cobalt -rich skarn iron deposit; LA-ICP-MS; EASTERN CHINA; CU-FE; SOUTHEASTERN HUBEI; TRACE-ELEMENT; LOWER REACHES; ORE FIELD; PORPHYRY; PETROGENESIS; COPPER;
D O I
10.18654/1000-0569/2023.10.10
中图分类号
P5 [地质学];
学科分类号
0709 ; 081803 ;
摘要
Cobalt, being a vital strategic rare and precious metal, is primarily produced within diverse deposit types through co association. The cobalt -rich skarn iron deposit is a key deposit type with considerable development potential. However, the source and enrichment mechanism of cobalt in skarn iron deposit remain unclear. The Zhuchong cobalt -rich skarn iron deposit is located in the Anqing-Guichi district of the Middle -Lower Yangtze River Valley Metallogenic Belt ( MLYB). It is the first large-scale skarn iron -rich deposit discovered in the metallogenic belt in recent years. Its associated cobalt resources have reached a medium scale. Meanwhile, the cobalt grade in the Zhuchong cobalt -rich skarn iron deposit is the highest among similar deposits in the MLYB, reaching 190g/t. In this study, the zircon U-Pb dating of the ore -forming intrusions and the spatial variation of pyrite in -situ sulfur isotopes in the vertical direction ( drilling section) of the Zhuchong cobalt -rich skarn iron deposit were carried out. The results indicate that the U-Pb ages of the two deep concealed magmatic rock samples are 139. 6 +/- 1. 0Ma and 138. 9 +/- 0. 6Ma, respectively, which occurred during the Early Cretaceous. Vertically, the overall range of pyrite sulfur isotope is +5. 3%similar to + 13. 9%o, and delta S-34 varies greatly from top to bottom, and shows strong heterogeneity, which is obviously different from the sulfur isotope compositions of Anqing skarn Cu -Fe deposit. The pyrite delta S-34 in the cobalt -rich magnetite ore body in the bottom -up mineralization -alteration zone of the Zhuchong deposit ranges from 5. 3%o to 10. 0%o. In the diopside skarn belt near the ore, the delta S-34 range of the vein pyrite spans from 12. 1%o to 13. 9%o. Within the altered diorite, the delta S-34 values of vein pyrite vary from 7. 1%o to 10. 8%o. In the outer skarn, the delta S-34 range of vein pyrite ranges fall between 6. 8%o and 7. 6%o. Within the siltstone of the Yueshan Formation, located in the gypsum -bearing salt layer, the delta S-34 values of pyrite range from 12. 0%o to 12. 7%o. Similarly, the uppermost siltstone vein pyrite of the Tongtoujian Formation exhibits a delta S-34 range of 6. 1%o to 7. 8%o. The sulfur isotope composition of pyrite within the Zhuchong cobalt -rich magnetite ore exhibits an intermediate range between that of the Yueshan pluton and the gypsum -salt layer of the Yueshan Formation. This suggests that the sulfur isotope signature within the ore reflects a mixture of two distinct end members. Statistical analysis of scale and grade within the MLYB cobalt -rich skarn deposits ( Fe -Cu -Co) indicates no apparent correlation between cobalt mineralization and the type of Fe -Cu skarn deposits. Furthermore, the involvement of sulfur through the gypsum -salt layer in the ore -forming hydrothermal fluid does not exhibit a discernible
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页码:3015 / 3030
页数:16
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