Recent progress in modifications of g-C3N4 for photocatalytic hydrogen evolution and CO2 reduction

被引:0
|
作者
Rana, Garima [1 ]
Dhiman, Pooja [1 ]
Kumar, Amit [1 ,2 ]
Dawi, Elmuez A. [3 ]
Sharma, Gaurav [2 ]
机构
[1] Shoolini Univ, Int Res Ctr Nanotechnol Himalayan Sustainabil IRCN, Solan 173229, India
[2] Shenzhen Univ, Guangdong Res Ctr Interfacial Engn Funct Mat, Nanshan Dist Key Lab Biopolymers & Safety Evaluat, Coll Mat Sci & Engn,Shenzhen Key Lab Polymer Sci &, Shenzhen 518060, Peoples R China
[3] Ajman Univ, Dept Math & Sci, Coll Humanities & Sci, POB 346, Ajman, U Arab Emirates
关键词
g-C3N4; H-2; evolution; CO2; reduction; modification; photocatalysis; GRAPHITIC CARBON NITRIDE; CHARGE-CARRIER SEPARATION; IN-SITU SYNTHESIS; Z-SCHEME; H-2; PRODUCTION; (G-C3N4)-BASED PHOTOCATALYSTS; HETEROSTRUCTURE PHOTOCATALYST; HETEROJUNCTION PHOTOCATALYST; ENVIRONMENTAL REMEDIATION; COMPOSITE PHOTOCATALYSTS;
D O I
10.1088/1361-6641/ad0eea
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Photocatalytic H-2 evolution and CO2 reduction are promising technologies for addressing environmental and energy issues. g-C3N4 is one of most promising materials to form improved catalysts because of its exceptional electrical structure, physical and chemical characteristics, and distinctive metal-free feature. This article provides a summary of current advancements in g-C3N4-based catalysts from innovative design approaches and their applications. Hydrogen evolution has reached 6305.18 mu mol g(-1) h(-1) and >9 h of stability using the SnS2/g-C3N4 heterojunction. Additionally, the ZnO/Au/g-C3N4 maintains a constant CO generation rate of 689.7 mol m(-2) during the 8 h reaction. To fully understand the interior relationship of theory-structure performance on g-C3N4-based materials, modifications are studied simultaneously. Furthermore, the synthesis of g-C3N4 and g-C3N4-based materials, as well as their respective instances, have been reported. The reduction of CO2 and H-2 generation is summarized. Lastly, a short overview of the present issues and potential alternatives for g-C3N4-based materials is provided.
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页数:23
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