Experimental and numerical investigation of combustion characteristics of carbon-free NH3/H2 blends in N2O

A detailed experimental and numerical investigation of the combustion characteristics of carbon-free NH3/H2 blends in N2O was performed in the present work. The experiments with various hydrogen fractions (a = 0-1.0) and equivalence ratios (4 = 0.6-1.4) were performed at ambient pressure (1 atm) and temperature (283 K) in a standard 3.375-L cubic combustion vessel. The explosion behaviors (maximum explosion pressure Pmax and maximum pressure rise rate (dp/dt)max) were obtained from the pressure-time curves. Further, the combustion characteristics (e.g. laminar burning velocity (SL), thermal expansion ratio (s), flame thickness (d), effective Lewis number (Leeff) and Markstein length (Lb)) were calculated numerically by means of chemical kinetic analysis using Zhang's mechanism (Zhang et al., Combust. Flame, 2017, 182: 122-141). Besides, sensitivity analyses of the explosion pressure and laminar burning velocity were performed to identify the contribution of dominant elementary reactions. The results show that, for combustion supported by N2O, the flame instability and the potential of deflagration to detonation transition (DDT) should be considered for the evaluation of Pmax and (dp/dt)max. Moreover, the hydrodynamic instability of premixed H2/NH3/N2O flame reaches its peak near the stoichiometric ratio and increases monotonously with the hydrogen fraction. The diffusion-thermal instability is more significant in the leaner mixture, and it is not invariably enhanced with the increase of hydrogen fraction but is relevant to the compo-sition of the mixture. In addition, the sensitivity analysis of explosion pressure demon-strates that R80 (N2O + H2]N2+H2O) and R70 (N2O+(M) = N2+O (+M)) are the most dominant reactions contributing to the pressure rise. The sensitivity analysis of laminar burning velocity shows that R70 (N2O+(M) = N2+O (+M)), R71 (N2O + H=N2+OH) and R80 (N2O + H2=N2+H2O) are the most dominant reactions enhancing laminar burning velocity.(c) 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.