Visible-Light-Induced and Iodoform-Promoted Functionalization of Ether with Secondary Sulfonyl Amides

被引：2

作者：

Zhang, Fengrong ^{[1
]}

Liu, Lanqin ^{[1
]}

Chen, Xiaoyun ^{[2
]}

Hou, Hong ^{[1
]}

Han, Ying ^{[1
]}

Yan, Chaoguo ^{[1
]}

Shi, Yaocheng ^{[1
]}

Zhu, Shaoqun ^{[1
]}

机构：

[1] Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225009, Peoples R China

[2] Jiangsu Univ Sci & Technol, Sch Environm & Chem Engn, Zhenjiang 212005, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 89卷 / 01期

基金：

中国国家自然科学基金;

关键词：

C-H AMINATION; N BOND-FORMATION; HEMIAMINAL ETHERS; ALKYL ETHERS; AZOLES; CYCLIZATION; TETRAZOLES; ADJACENT; STRATEGY;

D O I：

10.1021/acs.joc.3c01545

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An iodoform-promoted functionalization of ether with secondary sulfonyl amides under visible-light irradiation was developed toward synthesis of hemiaminal skeleton with good to excellent isolated yields. The characterization of the isolated ether and iodoform complex revealed regioselective hydrogen atom transfer to initiate carbon radical formation and enabled the amination reaction with the sulfonamide.

引用

页码：687 / 691

页数：5

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