Synthesis of Isothiocyanates from Primary Amines via Visible-Light Photocatalysis

被引：9
|
作者：
Ma, Jinglin [1 ]
Li, Fengxi [1 ]
Wang, Chunyu [2 ]
Wang, Zhi [1 ]
Du, Chuang [3 ]
Wang, Lei [1 ]
机构：
[1] Jilin Univ, Sch Life Sci, Key Lab Mol Enzymol & Engn, Minist Educ, Changchun 130023, Peoples R China
[2] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130023, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Jilin, Peoples R China
来源：
ORGANIC LETTERS | 2023年 / 25卷 / 30期
关键词：
CHEMISTRY; THIOUREAS; APOPTOSIS; CELLS;
D O I：
10.1021/acs.orglett.3c02193
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A photocatalyzed, efficient, and mild approach for thesynthesisof various substituted isothiocyanates from amine and carbon disulfidewas reported in this work. This approach expands the scope of photocatalyticapplications and provides a new method for the preparation of aliphaticand aromatic isothiocyanates, which are significant organic buildingblocks and biological diagnostic markers.
引用
收藏
页码：5692 / 5696
页数：5
相关论文
共 50 条
  • [21] Tuning Nanostructures of Hematite for Visible-Light Photocatalysis
    Yu Lianqing
    Dong Kaituo
    Zhang Zhiping
    Hao Lanzhong
    Zhang Yaping
    ENERGY AND ENVIRONMENT FOCUS, 2015, 4 (04) : 330 - 333
  • [22] Anti-Markovnikov hydrochlorination and hydronitrooxylation of α-olefins via visible-light photocatalysis
    Jungwon Kim
    Xiang Sun
    Boris Alexander van der Worp
    Tobias Ritter
    Nature Catalysis, 2023, 6 : 196 - 203
  • [23] Decarboxylative Cyanation of Aliphatic Carboxylic Acids via Visible-Light Flavin Photocatalysis
    Ramirez, Nieves P.
    Koenig, Burkhard
    Gonzalez-Gomez, Jose C.
    ORGANIC LETTERS, 2019, 21 (05) : 1368 - 1373
  • [24] Anti-Markovnikov hydrochlorination and hydronitrooxylation of α-olefins via visible-light photocatalysis
    Kim, Jungwon
    Sun, Xiang
    van der Worp, Boris Alexander
    Ritter, Tobias
    NATURE CATALYSIS, 2023, 6 (02) : 196 - 203
  • [25] THE SYNTHESIS OF ISOTHIOCYANATES FROM AMINES
    HODGKINS, JE
    ETTLINGER, MG
    JOURNAL OF ORGANIC CHEMISTRY, 1956, 21 (04): : 404 - 405
  • [26] Exploration of Visible-Light Photocatalysis in Heterocycle Synthesis and Functionalization: Reaction Design and Beyond
    Chen, Jia-Rong
    Hu, Xiao-Qiang
    Lu, Liang-Qiu
    Xiao, Wen-Jing
    ACCOUNTS OF CHEMICAL RESEARCH, 2016, 49 (09) : 1911 - 1923
  • [27] Synthesis of Oxygenated Sesquiterpenoids Enabled by Combining Metabolic Engineering and Visible-Light Photocatalysis
    Liu, Chenguang
    Cui, Xiaoyi
    Chen, Wei
    Ma, Xiaoqiang
    Prather, Kristala J.
    Zhou, Kang
    Wu, Jie
    CHEMISTRY-A EUROPEAN JOURNAL, 2022, 28 (46)
  • [28] Solvothermal synthesis of designed nonstoichiometric strontium titanate for efficient visible-light photocatalysis
    Sulaeman, Uyi
    Yin, Shu
    Sato, Tsugio
    APPLIED PHYSICS LETTERS, 2010, 97 (10)
  • [29] Synthesis of substituted imid(thi)azolidines by [3+2] cycloaddition of aziridines with nitriles(isothiocyanates) via visible light photocatalysis
    Ye, Qianwen
    Xu, Xiaoliang
    Cheng, Dongping
    Guan, Baochuan
    Ye, Hongfeng
    Li, Xiaonian
    ARKIVOC, 2017, : 314 - 326
  • [30] The Coupling of Tertiary Amines with Acrylate Derivatives via Visible-Light Photoredox Catalysis
    Dai, Xiaojun
    Cheng, Dongping
    Guan, Baochuan
    Mao, Wenjuan
    Xu, Xiaoliang
    Li, Xiaonian
    JOURNAL OF ORGANIC CHEMISTRY, 2014, 79 (15): : 7212 - 7219
12345