Synthesis and crystal structure of the zinc borate Zn6B22O39<middle dot>H2O

被引：0
|
作者：
Ziegler, Raimund [1 ]
Huppertz, Hubert [1 ]
机构：
[1] Univ Innsbruck, Dept Gen Inorgan & Theoret Chem, Innrain 80-82, A-6020 Innsbruck, Austria
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2023年 / 78卷 / 11-12期
关键词：
zinc borate; high-pressure/high-temperature synthesis; crystal structure;
D O I：
10.1515/znb-2023-0089
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and crystal structure of Zn6B22O39<middle dot>H2O are described. This new zinc borate was synthesized at 7 GPa and 1523 K in a multianvil device. It crystallizes in the orthorhombic space group Pnma (no. 62) with the lattice parameters a = 818.77(4), b = 768.42(3), c = 1744.82(9) pm, V = 1.09777(9) nm(3), and two formula units per unit cell (Z = 2). The structure is closely related to those of M6B22O39<middle dot>H2O (M = Fe, Co, Ni, Cd) and features non-planar (BO3) units as demonstrated by single-crystal and powder X-ray diffraction techniques.
引用
收藏
页码：567 / 573
页数：7
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