Exothermic Processes in Nitric Solutions Containing Acetohydroxamic Acid

被引：1
|
作者：
Belova, E. V. [1 ]
Nazin, E. R. [1 ]
Kalistratova, V. V. [1 ]
Obedkov, A. S. [1 ]
机构：
[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119071, Russia
来源：
RADIOCHEMISTRY | 2023年 / 65卷 / 01期
关键词：
acetohydroxamic acid; nitric acid; thermal stability; parameters of exothermic processes; explosion safety; EXTRACTION;
D O I：
10.1134/S1066362223010125
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The thermal stability of 5-12 M HNO3 solutions containing 5-50 g/L acetohydroxamic acid was studied at atmospheric and above atmospheric pressure. It was established that at temperatures below the boiling point, solutions undergo weak exothermic oxidation processes, accompanied by gas evolution. The problem of explosion safety in the evaporation of nitric acid solutions containing acetohydroxamic acid is analyzed based on the obtained characteristics of exothermic processes.
引用
收藏
页码：81 / 86
页数：6
相关论文
共 50 条
  • [31] The effect of acetohydroxamic acid on the distribution of Np(IV) and Np(VI) between 30% TBP and nitric acid
    Chung, Dong Yong
    Lee, Eil Hee
    JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 451 (1-2) : 440 - 442
  • [32] The effect of acetohydroxamic acid on the distribution of Np(IV) and Np(VI) between 30% TBP and nitric acid
    Department of Nuclear Chemical Engineering, Korea Atomic Energy Research Institute, P.O. Box 105, Yuseong, Daejeon, 305-600, Korea, Republic of
    Journal of Alloys and Compounds, 1600, 451 (1-2): : 440 - 442
  • [33] CROWNS IN PROCESSES OF URANIUM AND ACTINOID EXTRACTION FROM NITRIC-ACID SOLUTIONS
    YAKSHIN, VV
    FILIPPOV, EA
    BELOV, VA
    ARKHIPOVA, GG
    ABASHKIN, VM
    LASKORIN, BN
    DOKLADY AKADEMII NAUK SSSR, 1978, 241 (01): : 159 - 162
  • [34] Behaviors of Plutonium and Neptunium in Nitric Acid Solutions Containing Hydrazine and Technetium Ions
    Marchenko, V. I.
    Zhuravleva, G. I.
    Dvoeglazov, K. N.
    Savilova, O. A.
    THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2008, 42 (05) : 733 - 739
  • [35] Behaviors of plutonium and neptunium in nitric acid solutions containing hydrazine and technetium ions
    V. I. Marchenko
    G. I. Zhuravleva
    K. N. Dvoeglazov
    O. A. Savilova
    Theoretical Foundations of Chemical Engineering, 2008, 42 : 733 - 739
  • [36] Effect of temperature on NOx absorption into nitric acid solutions containing hydrogen peroxide
    Thomas, D
    Vanderschuren, J
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1998, 37 (11) : 4418 - 4423
  • [37] Corrosion Performance of Stainless Steels in Nitric Acid Solutions Containing Fission Products
    Corros Eng, 5 (309):
  • [38] Corrosion mechanism of stainless steel in nitric acid solutions containing ruthenium compounds
    Arai, Yuko
    Sasahira, Akira
    Honda, Takashi
    Zairyo to Kankyo/ Corrosion Engineering, 1999, 48 (04): : 235 - 241
  • [39] RADIOLYSIS GASES FROM NITRIC-ACID SOLUTIONS CONTAINING HSA AND HAN
    SMITH, JR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 210 : 23 - NUCL
  • [40] DETERMINATION OF NITRIC-ACID IN SOLUTIONS CONTAINING HYDROLYZING METAL-IONS
    STABROVSKII, AI
    KARASEV, AF
    KRIVTSOVA, LP
    ZAVODSKAYA LABORATORIYA, 1975, 41 (08): : 940 - 940
12345