Green synthesized carbon aerogel for electric double layer capacitor

被引:14
|
作者
Patil, Ashwini V. [1 ]
Sawant, Suman A. [2 ]
Sonkawade, Rajendra G. [2 ]
Vhatkar, Rajiv S. [1 ]
机构
[1] Shivaji Univ, Dept Phys, Space & Mat Lab, Kolhapur 416004, Maharashtra, India
[2] Shivaji Univ, Dept Phys, Radiat & Mat Res Lab, Kolhapur 416004, Maharashtra, India
关键词
Carbon aerogel; Carbonization; Green synthesis; Hydrothermal route; Sugarcane juice; Supercapacitors; HIERARCHICAL POROUS CARBON; BIOMASS-DERIVED CARBON; ENERGY-STORAGE; SURFACE-AREA; PERFORMANCE; COMPOSITES; MICROSPHERES; POROSITY;
D O I
10.1016/j.est.2023.108533
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
As new-generation biomass-derived carbon materials, carbon aerogels offer opportunities in supercapacitor applications. Owing to their excellent properties viz., a synergy of unique interconnected hierarchical porous structure, high specific surface area (SSA), and electrical conductivity they prove their candidature in electric double layer capacitors (EDLCs). In this article, we represent a green synthesis of carbon aerogel using sugarcane juice as a carbon source via cost effective hydrothermal method instead of the traditional supercritical drying method which is more toxic, time-consuming, and expensive. The structural and compositional studies confirm the formation of Sugar Aerogel (SA). Additionally, the surface analysis shows the interconnected porous scoop like structure with a high SSA of 2028 m2/g and a low bulk density of 0.08 g/cc. Furthermore, the synthesized powder was screen printed on flexible stainless-steel mesh to conduct electrochemical study at various Na2SO4 electrolyte concentrations (0.3, 0.6, 1.0, 2.0, 3.0 M). In 1.0 M Na2SO4 electrolyte, the SA showed 70% retention rate after 5500 cycles at 30 mA/cm2 current density over 1.9V potential window and also provides high energy density and power density 61.72 Wh/kg and 1588.33 W/kg respectively. Also, the SA||SA device exhibits stability over 1000 cycles with a 30% increment in capacitance with energy and power density 86 Wh/kg and 7920 W/kg. This study signifies the great potential of sugarcane juice to get SA via a simple, cost-effective, and environmentally friendly hydrothermal route for the fabrication of SC electrodes in neutral electrolyte Na2SO4.
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页数:13
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