N-Oxyethylimidazolium Calix[4]arenes and Thiacalix[4]arenes: Difference in Solubilization Property and Detection of Adenine-Containing Nucleotides

被引：0

作者：

Sultanova, Elza D. ^{[1
]}

Gafiatullin, Bulat Kh. ^{[1
]}

Ocherednyuk, Evgeny A. ^{[1
]}

Garipova, Ramilya I. ^{[1
]}

Volodina, Anastasia A. ^{[1
]}

Daminova, Amina G. ^{[1
]}

Evtugyn, Vladimir G. ^{[1
]}

Burilov, Vladimir A. ^{[1
]}

Solovieva, Svetlana E. ^{[2
]}

Antipin, Igor S. ^{[1
]}

机构：

[1] Kazan Fed Univ, Kazan 420008, Russia

[2] Russian Acad Sci, Arbuzov Inst Organ & Phys Chem, FRC Kazan Sci Ctr, Kazan 420088, Russia

来源：

MACROHETEROCYCLES | 2023年 / 16卷 / 02期

基金：

俄罗斯科学基金会;

关键词：

Calix[4]arene; thiacalix[4]arene; surfactants; solubilization; sensors for adenosine phosphates; NONVIRAL VECTORS; EOSIN Y; AGGREGATION; MICELLAR; CALIXARENES; DERIVATIVES; DELIVERY; SYSTEM; DYES;

D O I：

10.6060/mhc235118s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The properties of amphiphilic calix[4]arenes and thiacalix[4]arenes containing the same polar N-tetrahydroxyethylimidazolium groups on one side and alkyl fragments on the other side of the macrocyclic platform are shown. Critical aggregation concentration (CAC) values were studied with three methods: solubilization of Orange OT (a); binding of pyrene (b); interaction with eosin Y (c). Absorbance and emission plots of interaction with eosin Y were effectively calculated by a sigmoidal Boltzmann type function. Different solubilizing ability, interaction with a dianion dye, and selectivity of the of binary system macrocycle-eosin Y respectively to adenosine phosphates (mono-, di-or triphosphate) are shown.

引用

页码：168 / 176

页数：9

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