N-Oxyethylimidazolium Calix[4]arenes and Thiacalix[4]arenes: Difference in Solubilization Property and Detection of Adenine-Containing Nucleotides

被引：0
|
作者：
Sultanova, Elza D. [1 ]
Gafiatullin, Bulat Kh. [1 ]
Ocherednyuk, Evgeny A. [1 ]
Garipova, Ramilya I. [1 ]
Volodina, Anastasia A. [1 ]
Daminova, Amina G. [1 ]
Evtugyn, Vladimir G. [1 ]
Burilov, Vladimir A. [1 ]
Solovieva, Svetlana E. [2 ]
Antipin, Igor S. [1 ]
机构：
[1] Kazan Fed Univ, Kazan 420008, Russia
[2] Russian Acad Sci, Arbuzov Inst Organ & Phys Chem, FRC Kazan Sci Ctr, Kazan 420088, Russia
来源：
MACROHETEROCYCLES | 2023年 / 16卷 / 02期
基金：
俄罗斯科学基金会;
关键词：
Calix[4]arene; thiacalix[4]arene; surfactants; solubilization; sensors for adenosine phosphates; NONVIRAL VECTORS; EOSIN Y; AGGREGATION; MICELLAR; CALIXARENES; DERIVATIVES; DELIVERY; SYSTEM; DYES;
D O I：
10.6060/mhc235118s
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The properties of amphiphilic calix[4]arenes and thiacalix[4]arenes containing the same polar N-tetrahydroxyethylimidazolium groups on one side and alkyl fragments on the other side of the macrocyclic platform are shown. Critical aggregation concentration (CAC) values were studied with three methods: solubilization of Orange OT (a); binding of pyrene (b); interaction with eosin Y (c). Absorbance and emission plots of interaction with eosin Y were effectively calculated by a sigmoidal Boltzmann type function. Different solubilizing ability, interaction with a dianion dye, and selectivity of the of binary system macrocycle-eosin Y respectively to adenosine phosphates (mono-, di-or triphosphate) are shown.
引用
收藏
页码：168 / 176
页数：9
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