Polycobaltoceniumylmethylene - A Water-Soluble Polyelectrolyte Prepared by Ring-Opening Transmetalation Polymerization

被引：8

作者：

Feuerstein, Aylin ^{[1
]}

Bossmann, Blandine ^{[2
]}

Rittner, Till ^{[2
]}

Leiner, Regina ^{[2
]}

Janka, Oliver ^{[1
]}

Gallei, Markus ^{[2
,3
]}

Schafer, Andre ^{[1
]}

机构：

[1] Saarland Univ, Fac Nat Sci & Technol, Dept Chem, Inorgan Chem, D-66123 Saarbrucken, Germany

[2] Saarland Univ, Fac Nat Sci & Technol, Dept Chem, Polymer Chem, D-66123 Saarbrucken, Germany

[3] Saarene, Saarland Ctr Energy Mat & Sustainabil, D-66123 Saarbrucken, Germany

来源：

ACS MACRO LETTERS | 2023年 / 12卷 / 08期

关键词：

HIGH-MOLECULAR-WEIGHT; ORGANOMETALLIC POLYMERS; BLOCK-COPOLYMERS; REDOX PROPERTIES; COBALTICINIUM; METALLOPOLYMERS; POLY(FERROCENYLSILANES); COBALTOCENE; MONOMERS; BEHAVIOR;

D O I：

10.1021/acsmacrolett.3c00336

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis ofa water-soluble polycobaltoceniumylmethylene chloride(PCM-Cl) via ring-opening transmetalation polymerization is presented.Starting from a carba[1]magnesocenophane and cobalt(II) chloride,this route gives access to a polymer with methylene-bridged cobaltoceniummoieties within the polymers' main-chain. The polymer was characterizedby NMR spectroscopy, elemental analysis, TGA, DSC, XRD, and CV measurements,as well as UV-vis spectroscopy. Furthermore, GPC measurementsin an aqueous eluent versus pullulan standards were conducted to gaininsight into the obtained molar masses and distributions. In addition,the ion-dependent solubility was demonstrated by anion exchange, tuningthe hydrophobic/hydrophilic properties of this redox-responsive material.

引用

页码：1019 / 1024

页数：6

共 50 条

[1] A Water-Soluble Polycarbonate With Dimethylamino Pendant Groups Prepared by Enzyme-Catalyzed Ring-Opening Polymerization
Zhang, Xiaojin
Cai, Mengmeng
Zhong, Zhenlin
Zhuo, Renxi
MACROMOLECULAR RAPID COMMUNICATIONS, 2012, 33 (08) : 693 - 697
[2] Water-Soluble Poly(phosphonate)s via Living Ring-Opening Polymerization
Steinbach, Tobias
Ritz, Sandra
Wurm, Frederik R.
ACS MACRO LETTERS, 2014, 3 (03): : 244 - 248
[3] A UV VISIBLE SPECTROSCOPIC STUDY OF WATER-SOLUBLE CONJUGATED POLYENES PREPARED VIA THE RING-OPENING METATHESIS POLYMERIZATION REACTION
AMIREBRAHIMI, V
BYRNE, D
HAMILTON, JG
ROONEY, JJ
MACROMOLECULAR CHEMISTRY AND PHYSICS, 1995, 196 (01) : 327 - 342
[4] Living ring-opening metathesis polymerization in water via activation of water-soluble ruthenium alkylidenes.
Lynn, DM
Mohr, B
Grubbs, RH
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 215 : U365 - U365
[5] SYNTHESIS OF NOVEL HYDROPHOBICALLY-MODIFIED WATER-SOLUBLE POLYMERS BY RING-OPENING METATHESIS POLYMERIZATION
MCARDLE, CM
HAMILTON, JG
LAW, EE
ROONEY, JJ
MACROMOLECULAR RAPID COMMUNICATIONS, 1995, 16 (10) : 703 - 712
[6] Water-soluble polyphosphonate-based bottlebrush copolymers via aqueous ring-opening metathesis polymerization
Resendiz-Lara, Diego A.
Azhdari, Suna
Gojzewski, Hubert
Groschel, Andre H.
Wurm, Frederik R.
CHEMICAL SCIENCE, 2023, 14 (40) : 11273 - 11282
[7] SOLUBLE CATALYSTS OF RING-OPENING POLYMERIZATION OF CYCLOPENTENE
KHODZHEMIROV, VA
CHEREDNI.VM
EVDOKIMO.VA
VYSOKOMOLEKULYARNYE SOEDINENIYA SECTION B, 1972, 14 (10): : 727 - +
[8] REGIOCHEMISTRY OF POLYSILANES PREPARED BY RING-OPENING POLYMERIZATION
FOSSUM, E
MATYJASZEWSKI, K
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 76 - POLY
[9] Tandem Coordination, Ring-Opening, Hyperbranched Polymerization for the Synthesis of Water-Soluble Core-Shell Unimolecular Transporters
Popeney, Chris S.
Lukowiak, Maike C.
Boettcher, Christoph
Schade, Boris
Welker, Pia
Mangoldt, Dorothea
Gunkel, Gesine
Guan, Zhibin
Haag, Rainer
ACS MACRO LETTERS, 2012, 1 (05): : 564 - 567
[10] Ultrafast Monomer Emulsified Aqueous Ring-Opening Metathesis Polymerization for the Synthesis of Water-Soluble Polynorbornenes with Precise Structure
Hou, Wangmeng
Yin, Xiuzhe
Chen, Yao
Du, Jianzhong
Chen, Yongming
Shi, Yi
ACS MACRO LETTERS, 2023, 12 (06) : 794 - 800

← 1 2 3 4 5 →