Insights into non-covalent interactions in dicopper(<sc>ii</sc>,<sc>ii</sc>) complexes bearing a naphthyridine scaffold: anion-dictated electrochemistry

被引：2

作者：

De Tovar, Jonathan ^{[1
]}

Philouze, Christian ^{[1
]}

Thibon-Pourret, Aurore ^{[1
]}

Belle, Catherine ^{[1
]}

机构：

[1] Univ Grenoble Alpes, CNRS, DCM, UMR 5250, F-38000 Grenoble, France

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 16期

关键词：

Scaffolds;

D O I：

10.1039/d3cc06264c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A family of bis(mu-hydroxido)dicopper(ii,ii) complexes bearing a naphthyridine-based scaffold has been synthesized and characterized. Cyclic voltammetry reveals that the nature of the anions present in the complexes plays a pivotal role in their electrochemical properties. X-ray diffraction, spectroscopic and electrochemical analysis data support the formation of intimate ion pairs by non-covalent interactions driving to a ca. 270 mV difference for the potential required to monooxidize the (CuCuII)-Cu-II species.

引用

页码：2228 / 2231

页数：4

共 25 条

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