Insights into non-covalent interactions in dicopper(<sc>ii</sc>,<sc>ii</sc>) complexes bearing a naphthyridine scaffold: anion-dictated electrochemistry

被引：2
|
作者：
De Tovar, Jonathan [1 ]
Philouze, Christian [1 ]
Thibon-Pourret, Aurore [1 ]
Belle, Catherine [1 ]
机构：
[1] Univ Grenoble Alpes, CNRS, DCM, UMR 5250, F-38000 Grenoble, France
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 16期
关键词：
Scaffolds;
D O I：
10.1039/d3cc06264c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A family of bis(mu-hydroxido)dicopper(ii,ii) complexes bearing a naphthyridine-based scaffold has been synthesized and characterized. Cyclic voltammetry reveals that the nature of the anions present in the complexes plays a pivotal role in their electrochemical properties. X-ray diffraction, spectroscopic and electrochemical analysis data support the formation of intimate ion pairs by non-covalent interactions driving to a ca. 270 mV difference for the potential required to monooxidize the (CuCuII)-Cu-II species.
引用
收藏
页码：2228 / 2231
页数：4
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