Nickel-catalysed enantioselective reaction of secondary phosphine oxides and activated vinylcyclopropanes

被引：13
|
作者：
Huang, Zhuo [1 ]
Liu, Xu-Teng [1 ]
Cui, Ranran [1 ]
Zhang, Qing-Wei [1 ]
机构：
[1] Univ Sci & Technol China, Dept Chem, Key Lab Precis & Intelligent Chem, Hefei 230026, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 15期
关键词：
VINYL-CYCLOPROPANES; 3+2 CYCLOADDITION; ASYMMETRIC-SYNTHESIS; LIGANDS; ARYLATION; BORANES; RINGS;
D O I：
10.1039/d3ob00389b
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Activated vinylcyclopropanes can form zwitterionic pi-allylmetal species in the presence of transition metals and are widely used in organic synthesis. A nickel-catalyzed asymmetric allylation of secondary phosphine oxides with vinylcyclopropanes was described. Tertiary phosphine oxide products could be obtained with up to 91% yield and 92% ee.
引用
收藏
页码：3096 / 3100
页数：5
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