Bi2O3/ZnO heterostructured semiconductor nanocomposites: synthesis, characterization and its visible light-induced degradation of methylene blue dye

被引:1
|
作者
Simeyon, Velanganni [4 ,5 ]
Dinesh, Ayyar [6 ]
Deivatamil, Deivanayagam [7 ]
Thiruneelakandan, Raghavan [1 ]
Meena, Boominathan Catherin [8 ]
Mathavi, Manikandan [9 ]
Padmapriya, Govindaswamy [9 ]
Durka, Manikandan [10 ]
Ayyar, Manikandan [2 ,3 ]
Ansarie, Abuzar [11 ,12 ]
Hashem, Mohamed [13 ]
Fouad, Hassan [14 ]
机构
[1] Anna Univ, Univ Coll Engn, Dept Chem, BIT Campus, Tiruchirappalli 620024, Tamil Nadu, India
[2] Karpagam Acad Higher Educ, Dept Chem, Coimbatore 641021, Tamil Nadu, India
[3] Karpagam Acad Higher Educ, Ctr Mat Chem, Coimbatore 641021, Tamil Nadu, India
[4] Parvathys Arts & Sci Coll, Dept Chem, Dindigul 624002, India
[5] Madurai Kamaraj Univ, Madurai, India
[6] Univ Madras, Govt Arts Coll Men Autonomous, Dept Chem, Chennai 600035, Tamil Nadu, India
[7] Thanthai Periyar Govt Arts & Sci Coll Autonomous, PG & Res Dept Phys, Tiruchirappalli 620023, Tamil Nadu, India
[8] Bishop Heber Coll, Dept Chem, Tiruchirappalli 620017, Tamil Nadu, India
[9] Bharath Inst Higher Educ & Res BIHER, Fac Arts & Sci, Dept Chem, Chennai 600073, Tamil Nadu, India
[10] Bharath Inst Higher Educ & Res BIHER, Dept Phys, Chennai 600073, Tamil Nadu, India
[11] Ewha Womans Univ, Dept Obstet & Gynecol, Seoul 07984, South Korea
[12] Ewha Womans Univ, Ewha Med Res Inst, Coll Mediciane, Seoul 07984, South Korea
[13] King Saud Univ, Coll Appl Med Sci, Dept Dent Hlth, POB 12372, Riyadh, Saudi Arabia
[14] Helwan Univ, Fac Engn, Biomed Engn Dept, Helwan, Egypt
关键词
ZnO/Bi2O3; heterojunction; SILAR-CBD deposition; methylene blue dye; visible light; band gap energy; PHOTOCATALYTIC DEGRADATION; HETEROJUNCTION; COMPOSITE; PROPERTY;
D O I
10.1515/zpch-2023-0387
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, we describe the creation of linked semiconductor nanomaterials, which represents a significant development for photocatalytic applications. A Bi2O3-ZnO hetrostructured thin film was created using the SILAR-CBD deposition technique. In comparison to pure ZnO and Bi2O3, the produced heterostructured thin film showed greater photocatalytic (PCD) activity for the degradation of methylene blue (MB) dye under UV light. The formation of Bi2O3 (monoclinic lattice phase) and ZnO (hexagonal wurtzite phase) are the heterostructured nanomaterials that were generated, according to a powder XRD inspection. An image taken with HR-TEM demonstrates the mixing of nanoparticles and nanorod formations in the Bi2O3/ZnO. The vectorial movement of electrons (e-) and holes (h+) between ZnO and Bi2O3 is responsible for the boosted photocatalytic efficiency, which is in turn, accountable for the enhanced photocatalytic activities.
引用
收藏
页码:421 / 435
页数:15
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