Metal-Organic Framework (MOF)-Based Clean Energy Conversion: Recent Advances in Unlocking its Underlying Mechanisms

被引:3
|
作者
Zhu, Zheng [1 ]
Duan, Jingjing [1 ]
Chen, Sheng [1 ]
机构
[1] Nanjing Univ Sci & Technol, Sch Chem & Chem Engn, Sch Energy & Power Engn, Key Lab Soft Chem & Funct Mat,Minist Educ, Nanjing 210094, Peoples R China
关键词
clean energy conversion; electrocatalysis; mechanisms; metal-organic framework (MOF); OXYGEN REDUCTION REACTION; MOF-DERIVED ELECTROCATALYSTS; HYDROGEN EVOLUTION; NITROGEN REDUCTION; CARBON-DIOXIDE; N-C; BIFUNCTIONAL ELECTROCATALYSTS; ELECTROCHEMICAL REDUCTION; CATHODE MATERIALS; RECENT PROGRESS;
D O I
10.1002/smll.202309119
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Carbon neutrality is an important goal for humanity . As an eco-friendly technology, electrocatalytic clean energy conversion technology has emerged in the 21st century. Currently, metal-organic framework (MOF)-based electrocatalysis, including oxygen reduction reaction (ORR), oxygen evolution reaction (OER), hydrogen evolution reaction (HER), hydrogen oxidation reaction (HOR), carbon dioxide reduction reaction (CO2RR), nitrogen reduction reaction (NRR), are the mainstream energy catalytic reactions, which are driven by electrocatalysis. In this paper, the current advanced characterizations for the analyses of MOF-based electrocatalytic energy reactions have been described in details, such as density function theory (DFT), machine learning, operando/in situ characterization, which provide in-depth analyses of the reaction mechanisms related to the above reactions reported in the past years. The practical applications that have been developed for some of the responses that are of application values, such as fuel cells, metal-air batteries, and water splitting have also been demonstrated. This paper aims to maximize the potential of MOF-based electrocatalysts in the field of energy catalysis, and to shed light on the development of current intense energy situations. Metal-organic frameworks (MOFs) are emerging hot materials in the field of catalysis, exhibiting unique structural tunability, multifunctionality, and reproducibility, and their derivatives (also MOFs) are mostly applied in eco-friendly energy conversion electrocatalysis.image
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页数:46
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