PREPARATION OF NONIONIC WATER-SOLUBLE PHOSPHINES AND THEIR RHODIUM COMPLEXES FOR CATALYTC HYDROFORMYLATION OF OLEFIN

被引：0
|
作者：
YAN Yuan-Yong ZHUO Huan-Pei YANG Bo JIN Zi-LinCollege of Chemical Engineering Dalian University of Technology Dalian
机构：
来源：
Journal of Natural Gas Chemistry | 1994年 / 04期
基金：
中国国家自然科学基金;
关键词：
In; PREPARATION OF NONIONIC WATER-SOLUBLE PHOSPHINES AND THEIR RHODIUM COMPLEXES FOR CATALYTC HYDROFORMYLATION OF OLEFIN; IV; than; MPa;
D O I：
暂无
中图分类号：
O621.25 [];
学科分类号：
070303 ; 081704 ;
摘要：
Two kinds of nonionic water-soluble phosphine complexes:tri（o-polyglycol ether phenyl） phosphine（Ⅰ） and tri（p-polyglycol ether phenyl）phosphine（Ⅱ） （n=3～12） were prepared. Their thodium complexes preparedin sitn were used in aqueous/organic solvent two-phase system for catalytichydroformylation of olefin. The results implied that the surfactant phosphineligands for the biphasic hydroformylation of olefin shows good catalytic activityand selectivity,At 100 C and 6.0 MPa total pressure （CO/H=1:1） theconversion of （?） dodecene and selectivity to aldehyde were higher than 85%.The effects of different conditions on the hydrofurmylation reaction wereexamined.
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页码：436 / 441
页数：6
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