The first facile total synthesis of natural (3R,4R,6S)-3,4-epoxybisabola-7(14),10-dien-2-one

被引：0

作者：

Zhi Yong Tang~*

机构：

来源：

Chinese Chemical Letters | 2009年 / 20卷 / 09期

基金：

美国国家科学基金会;

关键词：

Alkylation; Epoxidation; Synthesis;

D O I：

暂无

中图分类号：

O6212. [];

学科分类号：

摘要：

3,4-Epoxybisabola-7(14),10-dien-2-one,a natural sesquiterpoind,was first synthesized from(-)-carvone through 7 steps,in an overall yield of 35.9%.The key step was the allylation and then a substrate-directable epoxidation was committed successfully.

引用

页码：1017 / 1018

页数：2

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