The first facile total synthesis of natural (3R,4R,6S)-3,4-epoxybisabola-7(14),10-dien-2-one

被引：0
|
作者：
Zhi Yong Tang~*
机构：
来源：
Chinese Chemical Letters | 2009年 / 20卷 / 09期
基金：
美国国家科学基金会;
关键词：
Alkylation; Epoxidation; Synthesis;
D O I：
暂无
中图分类号：
O6212. [];
学科分类号：
摘要：
3,4-Epoxybisabola-7(14),10-dien-2-one,a natural sesquiterpoind,was first synthesized from(-)-carvone through 7 steps,in an overall yield of 35.9%.The key step was the allylation and then a substrate-directable epoxidation was committed successfully.
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页码：1017 / 1018
页数：2
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