Synthesis, Structure, and Magnetic Properties of a New Selenite Compound CdNi(SeO3)2(H2O)2

被引：0
|
作者：
李锦阳 [1 ,2 ]
王琳 [2 ]
赵志颖 [2 ]
何长振 [2 ]
机构：
[1] College of Chemistry, Fuzhou University
[2] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Mater, Chinese Academy of Sciences
来源：
Chinese Journal of Structural Chemistry | 2020年 / 39卷 / 09期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.14102/j.cnki.0254-5861.2011-2646
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
A new selenite compound CdNi(SeO3)2(H2O)2has been obtained by a conventional hydrothermal method. This compound crystallizes in monoclinic system of space group C2/c, which exhibits a layer structure built by NiO6octahedra and SeO3trigonal pyramids running along the a-axis. The layers show a unique eight-rings hole network. The compound is stable at room temperature while the loss of H2O molecules happens with heating above 523 K. Magnetic measurements indicate that CdNi(SeO3)2(H2O)2is an antiferromagnet and possesses an antiferromagnetic ordering at TN= 15 K.
引用
收藏
页码：1694 / 1698
页数：5
相关论文
共 50 条
  • [31] Hydrothermal synthesis and structural characterization of a new layered vanadium selenite:: (C4N2H12)0.5[(VO)2(H2O)2(SeO3)2(HSeO3)]
    Dai, ZM
    Li, GH
    Shi, Z
    Liu, XM
    Feng, SH
    INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (10) : 890 - 893
  • [32] Two New Neptunyl(V) Selenites: A Novel Cation-Cation Interaction Framework in (NpO2)3(OH)(SeO3)(H2O)2•H2O and a Uranophane-Type Sheet in Na(NpO2)(SeO3)(H2O)
    Jin, Geng Bang
    Skanthakumar, S.
    Soderholm, L.
    INORGANIC CHEMISTRY, 2011, 50 (13) : 6297 - 6303
  • [33] Synthesis and Crystal Structure of New Hydrated Lead Selenite Nitrate Pb4(SeO3)3(NO3)2<middle dot>2H2O
    Siidra, O. I.
    Grishaev, V. Yu.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2024, 65 (07) : 1432 - 1438
  • [34] Synthesis and structure of lithium cadmium selenite hydroxide, LiCd2(SeO3)2(OH)
    Johnston, MG
    Harrison, WTA
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (08): : 1913 - 1916
  • [35] CRYSTAL-STRUCTURE OF PRH3(SEO3)2(SE2O5), A COMPOUND WITH SELENITE AND DISELENITE GROUPS
    KOSKENLINNA, M
    VALKONEN, J
    ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1977, 31 (06): : 457 - 460
  • [36] New copper selenites.: Part B:: Cu2(SeO3)2•H2O and Tl(III)2Cu3(SeO3)6
    Giester, G
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1999, 214 (05): : 305 - 308
  • [37] A novel vanadyl selenite templated by organic salt: [(VO)(H2O)2(SeO3)]2[(H2pipe)SO4]
    Zhaoxun Lian
    Changcang Huang
    Hanhui Zhang
    Hongfang Yang
    Yong Zhang
    Xinfu Yang
    Journal of Chemical Crystallography, 2004, 34 : 489 - 494
  • [38] A novel vanadyl selenite templated by organic salt:: [(VO)(H2O)2(SeO3)]2[(H2pipe)SO4]
    Lian, ZX
    Huang, CC
    Zhang, HH
    Yang, HF
    Zhang, Y
    Yang, XF
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2004, 34 (08) : 489 - 494
  • [39] Thermal behavior of ferric selenite hydrates (Fe2(SeO3)3*3H2O, Fe2(SeO3)3*5H2O) and the water content in the natural ferric selenite mandarinoite
    Holzheid, Astrid
    Charykova, Marina V.
    Krivovichev, Vladimir G.
    Ledwig, Brendan
    Fokina, Elena L.
    Poroshina, Ksenia L.
    Platonova, Natalia V.
    Gurzhiy, Vladislav V.
    CHEMIE DER ERDE-GEOCHEMISTRY, 2018, 78 (02) : 228 - 240
  • [40] Synthesis and characterization of a new layered vanadium selenite:: β-(H3NCH2CH2NH3)[VO)(SeO3)2]
    Dai, ZM
    Li, GH
    Shi, Z
    Fu, WS
    Dong, WJ
    Xu, J
    Feng, SH
    SOLID STATE SCIENCES, 2004, 6 (01) : 91 - 96
12345